ChemicalBook--->CAS DataBase List--->2691-41-0

2691-41-0

2691-41-0 Structure

2691-41-0 Structure
IdentificationBack Directory
[Name]

HMX
[CAS]

2691-41-0
[Synonyms]

hw4
HMX
HW 4
lx14-0
LX 14-0
Oktogen
OCTOGEN
beta Hmy
beta-HMX
beta-hmy
beta-hmy[qr]
hmx solution
HOMOCYCLONITE
octogen[desensitized]
LABOTEST-BB LT00044465
HMX,1X1ML, ACN 1000UG/ML
Homocyclonite, Octogen, HMX
Cyclotetramethylene tetramine
TETRAMETHYLENE TETRANITRAMINE
octogen[Water cut 15% or higher]
Cyclotetramethylene tetranitramine
Cyclotetramethylenetetranitroamine
1,3,5,7-Tetranitro-1,3,5,7-tetraazocane
Cyclotetramethylen-tetranitramin(α-Form)
Cyclotetramethylenetetranitramine(β-form)
octogen,cyclotetramethylenetetranitramine
Octahydro-1,3,5,7-Tetranitro-s-tetrazocine
1,3,5,7-tetranitro-1,3,5,7-tetrazocyclooctane
1,3,5,7-Tetraza-1,3,5,7-tetranitrocyclooctane
1,3,5,7-TETRANITRO-1,3,5,7-TETRAAZACYCLOOCTANE
5,7-tetrazocine,octahydro-1,3,5,7-tetranitro-3
1,3,5,7-Tetraaza-1,3,5,7-tetranitrocyclooctane
1,3,5,7-tetranitro-1,3,5,7-tetrazocane solution
Octogen (1,3,5,7-Tetranitro-1,3,5,7-tetrazocan)
1,3,5,7-TETRANITRO-OCTAHYDRO-1,3,5,7-TETRAZOCINE
OCTAHYDRO-1,3,5,7-TETRANITRO-1,3,5,7-TETRAZOCINE
3,5,7-Tetrazocine,octahydro-1,3,5,7-tetranitro-1
1,3,5,7-Tetrazocine,octahydro-1,3,5,7-tetranitro-
HMX (1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane)
cyclotetramethylenetetranitramine,[wetwith>=10%water]
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine,betaine
1,3,5,7-Tetranitro-1,3,5,7-tetrazocane solution, Cyclotetramethylene tetranitramine
[EINECS(EC#)]

220-260-0
[Molecular Formula]

C4H8N8O8
[MDL Number]

MFCD00181712
[MOL File]

2691-41-0.mol
[Molecular Weight]

296.16
Chemical PropertiesBack Directory
[Appearance]

Hexahydro-1,3,5-trinitro-S-triazine is a white crystalline compound.
[Melting point ]

281°
[Boiling point ]

437.77°C (rough estimate)
[density ]

Density (g/cm3): b=1.903; a=1.87; g=1.82; d=1.78
[refractive index ]

1.6910 (estimate)
[Fp ]

2℃
[storage temp. ]

2-8°C
[form ]

Colorless solid
[pka]

-16.32±0.20(Predicted)
[CAS DataBase Reference]

2691-41-0
[EPA Substance Registry System]

Cyclotetramethylenetetranitramine (2691-41-0)
Hazard InformationBack Directory
[Definition]

ChEBI: A tetrazocane that is 1,3,5,7-tetrazocane in which the hydrogen atom attached to each of the nitrogens is replaced by a nitro group.
[Uses]

In solid propellants and explosives.
[General Description]

A white crystalline solid. Melting point 281°C. Practically insoluble in water. Water slurry mitigates explosion hazard. Used in solid propellants and explosives. The primary hazard is the blast effect and not flying projectiles and fragments.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

HMX is a high explosive. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water. Presence of metal oxides increases thermal sensitivity. Wetting reduces sensitivity toward detonation.
[Health Hazard]

Fire may produce irritating, corrosive and/or toxic gases.
[Fire Hazard]

MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.
[Potential Exposure]

A potential danger to those involved in the manufacture of this material and its handling in munitions and solid-propellant manufacture. It is also used as a rat poison; a powerful military explosive; a base charge for detonators; and in plastic explosives.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ- ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a Medical facility. When this chemical has been swallowed, get medi- cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[Shipping]

UN0483 Cyclotrimethylenetrinitramine, desensi- tized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized, Hazard Class: 1D; Labels: 1D- Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or frag- ment hazard) when exposed to fire. UN0072 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not ,15% water by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or fragment hazard) when exposed to fire.
[Incompatibilities]

Heat, physical damage, shock, and deto- nators. Detonates on contact with mercury fulminate. Keep away from other explosives, combustibles, oxidizers (such as chlorates, nitrates, perchlorates, permanganates, perox- ides; bromine, chlorine, and fluorine); reducing agents; and aqueous alkaline solutions.
[Chemical Properties]

Hexahydro-1,3,5-trinitro-S-triazine is a white crystalline compound.
[Chemical Properties]

HMX (high-melting explosive) is a completely N-nitrated, eight-membered heterocyclic ring compound analogous to RDX. HMX has a molecular weight of 296.16 and a melting point of 204°C. Virtually none of the toxicity information on HMX was published, but it was reviewed by the EPA.
[Waste Disposal]

Pour over soda ash, neutralize and flush to sewer with water. Also HMX may be recov- ered from solid propellant waste.
Safety DataBack Directory
[Hazard Codes ]

F,T,Xn,E
[Risk Statements ]

11-23/24/25-36/37/38-36-20/21/22-3
[Safety Statements ]

16-27-45-36/37-35-26
[RIDADR ]

0226
[WGK Germany ]

2
[HazardClass ]

1.1D
[HS Code ]

29339900
[Safety Profile]

A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279OC. When heated to decomposition it emits toxicfumes of NOx. See also EXPLOSIVES, HIGH.
[Hazardous Substances Data]

2691-41-0(Hazardous Substances Data)
[Toxicity]

LD50 oral in rabbit: 50mg/kg
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