SODIUM COBALTINITRITE
- CAS No.
- 13600-98-1
- Chemical Name:
- SODIUM COBALTINITRITE
- Synonyms
- SODIUM CLORIDE;SODIUM HEXANITROCOBALTATE(III);SODIUM COBALTNITRITE;SODIUM HEXANITROCOBALTATE;SODIUM HEXANITRITOCOBALTATE(III);Sodium hexanitrocoba;SODIUM COBALTINITRITE;COBALT SODIUM NITRITE;Cobaltnitrite, Sodium;SodiumCobaltinitriteGr
- CBNumber:
- CB2664428
- Molecular Formula:
- CoN6NaO12(-2)
- Molecular Weight:
- 357.95
- MDL Number:
- MFCD00003512
- MOL File:
- 13600-98-1.mol
- MSDS File:
- SDS
Melting point | 220 °C (dec.)(lit.) |
---|---|
storage temp. | Store below +30°C. |
solubility | 720g/l |
form | Solid |
color | Orange to orange-brown |
Odor | Odorless |
PH | 5 (100g/l, H2O, 20℃) |
Oxidising Properties | The substance or mixture is classified as oxidizing with the subcategory 2 |
Water Solubility | Soluble in water |
Merck | 13,8677 |
Stability | Stable. Contact with conbustible material may cause fire. Incompatible with strong acids, organic materials, amines. |
CAS DataBase Reference | 13600-98-1(CAS DataBase Reference) |
FDA UNII | XO0NGY9EY7 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS03,GHS07,GHS08 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H272-H315-H317-H319-H334-H335-H351 | |||||||||
Precautionary statements | P210-P280-P302+P352-P304+P340+P312-P305+P351+P338-P308+P313 | |||||||||
Hazard Codes | O,Xn | |||||||||
Risk Statements | 8-36/37/38-42/43-40 | |||||||||
Safety Statements | 17-26-36/37 | |||||||||
RIDADR | UN 1479 5.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | GF9480000 | |||||||||
HazardClass | 5.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 28429090 | |||||||||
NFPA 704 |
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SODIUM COBALTINITRITE price More Price(21)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 233722 | Sodium hexanitrocobaltate(III) ACS reagent | 13600-98-1 | 100g | $187 | 2024-03-01 | Buy |
Sigma-Aldrich | 233722 | Sodium hexanitrocobaltate(III) ACS reagent | 13600-98-1 | 500g | $636 | 2024-03-01 | Buy |
Sigma-Aldrich | 1.02521 | Sodium hexanitrocobaltate(III) [sodium cobalt(III)nitrite] for analysis EMSURE? ACS,Reag. Ph Eur | 13600-98-1 | 25g | $128 | 2024-03-01 | Buy |
Sigma-Aldrich | 1.02521 | Sodium hexanitrocobaltate(III) [sodium cobalt(III)nitrite] for analysis EMSURE? ACS,Reag. Ph Eur | 13600-98-1 | 100g | $257 | 2024-03-01 | Buy |
Strem Chemicals | 93-1056 | Sodium hexanitritocobaltate(III), (ACS) | 13600-98-1 | 50g | $123 | 2024-03-01 | Buy |
SODIUM COBALTINITRITE Chemical Properties,Uses,Production
Chemical Properties
SODIUM COBALTINITRITE is deep yellow to brown crystalline powder
Uses
SODIUM COBALTINITRITE is used in the detection Potassium.
Uses
For the detection of potassium with which it forms a slightly soluble compound.
Uses
Nitrosation reagent for the conversion of aromatic amines to 1,3-diaryltriazenes with excellent yield.1
Preparation
Sodiumhexanitrocobaltate(III) ("sodiumcobaltinitrite") Na3Co(N02)6
is a well-known orange solid which precipitates potassium ions from aqueous solution as
K3Co(NO2)6. It is prepared by blowing air through a mixture of cobalt(II) nitrate and
sodium nitrite solutions in the presence of acetic acid:
2[Co(H20)6]2+ +12NO2- +2CH3COOH + 1/2O2 → 2[Co(NO)2)6]3- +2CH3COO-+ 13H2O
after filtration of any precipitated potassium or ammonium salts, the sodium salt is precipitated
by the addition of ethanol.
Purification Methods
Dissolve the salt (ca 60g) in H2O (300mL), filter to obtain a clear solution, add 96% EtOH (250mL) with vigorous stirring. Allow the precipitate to settle for 2hours, filter it off, wash it with EtOH (4 x 25mL), twice with Et2O and dry it in air [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1541 1965]. It forms yellow to brown crystals which are very soluble in H2O, are decomposed by acid and form an insoluble K salt. Used for estimating potassium.
SODIUM COBALTINITRITE Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
Shanghai Zheyan Biotech Co., Ltd. | 18017610038 | zheyansh@163.com | CHINA | 3620 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9126 | 58 |
LEAP CHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 24738 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18451 | 58 |
View Lastest Price from SODIUM COBALTINITRITE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2020-02-02 | SODIUM COBALTINITRITE
13600-98-1
|
US $1.00 / KG | 1KG | 98% HPLC | 10 tons | Career Henan Chemical Co |
- SODIUM COBALTINITRITE
13600-98-1
- US $1.00 / KG
- 98% HPLC
- Career Henan Chemical Co