Trifluoromethyl iodide
- CAS No.
- 2314-97-8
- Chemical Name:
- Trifluoromethyl iodide
- Synonyms
- CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
- CBNumber:
- CB7356124
- Molecular Formula:
- CF3I
Lewis structure
- Molecular Weight:
- 195.91
- MDL Number:
- MFCD00001060
- MOL File:
- 2314-97-8.mol
Melting point | <−78 °C(lit.) |
---|---|
Boiling point | −22.5 °C(lit.) |
Density | 2.361 |
vapor pressure | 540.5kPa at 25℃ |
refractive index | 1.379 |
Flash point | -22.5°C |
form | Gas |
Water Solubility | Slightly soluble in water. |
Sensitive | Light Sensitive |
BRN | 1732740 |
Stability | Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable. |
LogP | 2.41 at 22.85℃ |
CAS DataBase Reference | 2314-97-8(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 42A379KB0U |
NIST Chemistry Reference | Methane, trifluoroiodo-(2314-97-8) |
EPA Substance Registry System | Trifluoroiodomethane (2314-97-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS04,GHS07,GHS08 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H280-H341-H420 | |||||||||
Precautionary statements | P201-P202-P280-P308+P313-P410+P403-P502 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 68 | |||||||||
Safety Statements | 36/37 | |||||||||
RIDADR | UN 1956 2.2 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | PB6975000 | |||||||||
F | 27 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | T | |||||||||
HazardClass | 2.2 | |||||||||
HS Code | 2903780020 | |||||||||
NFPA 704 |
|
Trifluoromethyl iodide price More Price(17)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 171441 | Trifluoroiodomethane 99% | 2314-97-8 | 25g | $264 | 2024-03-01 | Buy |
Sigma-Aldrich | 171441 | Trifluoroiodomethane 99% | 2314-97-8 | 100g | $455 | 2024-03-01 | Buy |
Alfa Aesar | 041479 | Trifluoroiodomethane 97+% | 2314-97-8 | 25g | $369 | 2023-06-20 | Buy |
Alfa Aesar | 041479 | Trifluoroiodomethane 97+% | 2314-97-8 | 100g | $651 | 2023-06-20 | Buy |
Strem Chemicals | 09-7680 | Trifluoromethyliodide, min. 97% | 2314-97-8 | 100g | $654 | 2024-03-01 | Buy |
Trifluoromethyl iodide Chemical Properties,Uses,Production
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Reactions
Trifluoromethyl iodide reacts with [AuMeL] to give [AuMe2(CF3)L] and [AuIL](L = PMe3 or PMe2Ph), or [Au(CF3)L] and Mel (L = PPh3), or a mixture of these products (L = PMePh2). In some cases reaction of [AuMe(PMe3)] with CF3I gives [AuMe(CF3)I(PMe3)]. Evidence is presented that the reactions proceed, at least in part, by a free-radical chain mechanism.
Chemical Properties
colourless gas
Uses
Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,?-unsaturated ketones.
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Synthesis Reference(s)
Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042
Flammability and Explosibility
Not classified
Trifluoromethyl iodide Preparation Products And Raw materials
Raw materials
Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9340 | 55 |
BEYOND INDUSTRIES (CHINA) LIMITED | +86-21-52699951; +8613917686115 | sales@beyondindustriesgroup.com | China | 699 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21687 | 55 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 19368 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15954 | 58 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 7154 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
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View Lastest Price from Trifluoromethyl iodide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-04-05 | Trifluoromethyl iodide
2314-97-8
|
US $8.00-1.00 / kg | 1kg | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-06-15 | Trifluoromethyl iodide
2314-97-8
|
US $1310.00 / KG | 1KG | 98% | 1-10mt | Baoji Guokang Bio-Technology Co., Ltd. | ||
2023-04-09 | Trifluoromethyl iodide
2314-97-8
|
US $0.00-0.00 / kg | 1kg | 99.99% | 50000kg | Shandong Hemao New Materials Co., Ltd |
- Trifluoromethyl iodide
2314-97-8
- US $8.00-1.00 / kg
- 99%
- Henan Fengda Chemical Co., Ltd
- Trifluoromethyl iodide
2314-97-8
- US $1310.00 / KG
- 98%
- Baoji Guokang Bio-Technology Co., Ltd.
- Trifluoromethyl iodide
2314-97-8
- US $0.00-0.00 / kg
- 99.99%
- Shandong Hemao New Materials Co., Ltd
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