シアヌル酸クロリド 化学特性,用途語,生産方法
外観
白色〜わずかにうすい黄色, 結晶性粉末〜粉末
溶解性
アセトンに溶けやすく、水に溶けにくい。
用途
染料、医薬、農薬原料。
化学的特性
White Powder
使用
Cyanuric Chloride is extensively used in the preparation of the triazine-class pesticides and herbicides. Cyanuric chloride is also used as a precursor to dyes and crosslinking agents due to the react
ive chlorine atoms towards nucleophilic substitution reactions. Cyanuric chloride derivatives possess a large spectrum of activities as antibacterial and anticancer agents.
定義
ChEBI: A chloro-1,3,5-triazine in which the triazine ring is substituted on each carbon by chlorine. Its main use is in the preparation of the triazine-class pesticides.
調製方法
Cyanuric chloride is obtained by the trimerization of cyanogen
chloride in organic solvents, in the presence of acidic
catalysts, and carried out in a gaseous phase at 200–500C.
Cyanuric chloride is used as a chemical intermediate. It is the
precursor to the herbicide atrazine.
一般的な説明
A colorless crystalline solid with a pungent odor. Melting point 146°C. Density 1.32 g / cm3. Very slightly soluble in water. Toxic by ingestion and inhalation of vapors. Irritates skin and eyes. Used to make dyes.
空気と水の反応
Reacts exothermically with water, especially if catalyzed or heated, to generate fumes of hydrochloric acid. Very slightly soluble in water.
反応プロフィール
Cyanuric chloride reacts rapidly and exothermically with water to generate hydrogen chloride. A mixture with water in an industrial reactor with refrigeration turned off developed pressure that blew gaskets and filled the building with flammable vapors. An explosion occurred when the vapors were ignited [MCA Case History 1869(1972)]. Runaway reactions have occurred with acetone/water; methanol/water, ethoxyethanol/water, allyl alcohol/sodium hydroxide/water, 2-butanone/sodium hydroxide/water, and methanol/sodium bicarbonate [Loss Prev. Bull., 1979, (25), 21]. Reacts with methanol to give gaseous methyl chloride. Reacts rapidly with bicarbonates to generate gaseous carbon dioxide. Reacts vigorously with dimethyl formamide (DMF) to form carbon dioxide after a deceptive induction period [BCISC Quart. Safety Summ., 1960, 35, 24]. Can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air).
健康ハザード
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
火災危険
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
安全性プロファイル
Poison by ingestion,
inhalation, and intravenous routes.
Questionable carcinogen with experimental
tumorigenic data. Experimental
reproductive effects. A corrosive. A skin and
severe eye irritant. An allergen. Has been
reported as causing irritation of mucous
membranes and heart rhythm disturbances
in humans. Violent reaction with water -
(above 30°C), acetone + water, methanol,
methanol + sodium hydrogen carbonate, 2-
ethoxyethanol, dimethyl formamide, 3-
butanone + sodium hydroxide + water, allyl
alcohol + sodium hydroxide + water (at
28℃). When heated to decomposition it
emits toxic fumes of Cland NOx. See also
CHLORIDES.
純化方法
TCT crystallises from CCl4 or pet ether (b 90-100o) and is dried under vacuum. It has also been recrystallised twice from anhydrous *benzene immediately before use [Abuchowski et al. J Biol Chem 252 3582 1977]. [Beilstein 26 III/IV 66.]
シアヌル酸クロリド 上流と下流の製品情報
原材料
準備製品
ミカシオンブルー3GS
1,1'-[4,1-フェニレンビスイミノビス(4-クロロ-1,3,5-トリアジン-2,6-ジイルイミノ)]ビス[7-[(2-スルホフェニル)アゾ]-8-ヒドロキシナフタレン-3,6-ジスルホン酸]
4,4'-ビス[[4-[4-(ソジオオキシスルホニル)アニリノ]-6-[ビス(2-ヒドロキシエチル)アミノ]-1,3,5-トリアジン-2-イル]アミノ]スチルベン-2,2'-ジスルホン酸ジナトリウム
2-[1-ヒドロキシ-3-[(ソジオオキシ)スルホニル]-6-[メチル(4,6-ジクロロ-1,3,5-トリアジン-2-イル)アミノ]ナフタレン-2-イルアゾ]ナフタレン-1,5-ビス(スルホン酸ナトリウム)
Reactive Disperse Scarlet G
Reactive Red M-3BE
C.I. Reactive yellow 1
2-(4-クロロ-6-エチルアミノ-1,3,5-トリアジン-2-イル)アミノ-2-メチルプロピオノニトリル
2,5-ジクロロ-4-[4-[[5-[[4-クロロ-6-[(4-スルホフェニル)アミノ]-1,3,5-トリアジン-2-イル]アミノ]-2-スルホフェニル]アゾ]-4,5-ジヒドロ-3-メチル-5-オキソ-1H-ピラゾール-1-イル]ベンゼンスルホン酸三ナトリウム
4-[[5-(アミノカルボニル)-1-エチル-2-ヒドロキシ-4-メチル-6-オキソ-3-ピペリジニル]アゾ]-6-[(4,6-ジクロロ-1,3,5-トリアジン-2-イル)アミノ]-1,3-ベンゼンジスルホン酸ジナトリウム
Reactive Red Violet X-2R
Direct Yellow L-5R
fluorescent whitening agent RA
Direct Blending Brilliant Red D-5BL
シマジン
N-エチル-N'-tert-ブチル-6-クロロ-1,3,5-トリアジン-2,4-ジアミン
Reactive Yellow 179
2-[[6-[(4-アミノ-6-クロロ-1,3,5-トリアジン-2-イル)(メチル)アミノ]-1-ヒドロキシ-3-スルホ-2-ナフチル]アゾ]-1,5-ナフタレンジスルホン酸三ナトリウム
C.I.リアクティブレッド195
Reactive Orange 2
5-[(4,6-ジクロロ-1,3,5-トリアジン-2-イル)アミノ]-4-ヒドロキシ-3-[[4-(フェニルアミノ)-3-スルホフェニル]アゾ]-2,7-ナフタレンジスルホン酸三ナトリウム
2-[[4-[[4-[ビス(2-ヒドロキシエチル)アミノ]-6-クロロ-1,3,5-トリアジン-2-イル]アミノ]フェニル]アゾ]-4-メチルフェノール
Direct Blend Rubine D-BLL
Reactive Red KD-8B
Neutral Brilliant Yellow S-5GL
2,4,6-トリフルオロ-1,3,5-トリアジン
Reactive Light Yellow M-5G
Prairie Net Wettable Powder
Reactive Brilliant Orange K-R
4,6-ジクロロ-N-(o-クロロフェニル)-1,3,5-トリアジン-2-アミン
プロシオンレッドH-E-7B
C.I.リアクティブイエロー18
4-[[4-[(4,6-ジクロロ-1,3,5-トリアジン-2-イル)アミノ]-2-スルホフェニル]アゾ]-4,5-ジヒドロ-5-オキソ-1-(4-スルホフェニル)-1H-ピラゾール-3-カルボン酸
リアクティブ エロ８４
Reactive Violet 2
3,3'-[(1,6-ジヒドロ-6-オキソ-1,3,5-トリアジン-2,4-ジイル)ビス[イミノ(5-メトキシ-2-メチル-4,1-フェニレン)アゾ]]ビス(1,5-ナフタレンジスルホン酸)四ナトリウム
Reactive Yellow KE-RN
アルトレタミン
C.I.リアクティブブルー171
N,N′-ジイソプロピル-6-(ジフルオロメチルチオ)-1,3,5-トリアジン-2,4-ジアミン