| Identification | Back Directory | [Name]
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos | [CAS]
1160861-53-9 | [Synonyms]
tBuBrettPhos
tBuBrettPhos 97%
t-butylBrettPhos
tertButylBrettPhos
tert-ButylBrettPhos
2-(Di-tert-butylphosphino)-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl
Di-tert-butyl(2',4',6'-triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine
2-(Di-t-butylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl
2-(Di-tert-butylphosphino)-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%
2-(Di-tert-butylphosphino)-2′,4′,6′- triisopropyl-3,6-dimethoxy-1,1′-biphenyl
Di-tert-butyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine
2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-3,6-dimethoxy-1,1'-biphenyl, (t-BuBrettPhos)
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, t-butylBrettPhos
2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (t-BuBrettPhos)
[3,6-Dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine
2-(Di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-BuBrettPhos
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos | [Molecular Formula]
C31H49O2P | [MDL Number]
MFCD13181930 | [MOL File]
1160861-53-9.mol | [Molecular Weight]
484.693 |
| Chemical Properties | Back Directory | [Melting point ]
166-170°C | [Boiling point ]
534.9±50.0 °C(Predicted) | [form ]
crystal | [color ]
white | [InChI]
InChI=1S/C31H49O2P/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12/h15-21H,1-14H3 | [InChIKey]
REWLCYPYZCHYSS-UHFFFAOYSA-N | [SMILES]
P(C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C)(C(C)(C)C)C(C)(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Ligand used in the Pd-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.
- Ligand used in the Pd-catalyzed O-arylation of ethyl acetohydroximates.
- Ligand used in the Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
- Ligand used in the Pd-catalyzed cross-coupling of amides and aryl mesylates.
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| Hazard Information | Back Directory | [Uses]
| [General Description]
tBuBrettPhos is a dialkylbiaryl phosphine ligand developed by the Buchwald group. It promotes cross-coupling reactions more efficiently and exhibits improved reactivity compared to other catalytic systems. |
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