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1212-08-4

1212-08-4 Structure

1212-08-4 Structure
IdentificationBack Directory
[Name]

BENZENETHIOSULFONIC ACID S-PHENYL ESTER
[CAS]

1212-08-4
[Synonyms]

NSC74657
Phenylphenylthiosulfone
Phenylbenzenethiosulfonate
S- phenylthiophenylsulfone
S-PHENYL BENZENETHIOSULFATE
(phenylthio)sulfonylbenzene
phenylsulfanylsulfonylbenzene
S-PHENYL BENZENETHIOSULFONATE
S-phenylbenzenethiosulphonate
S-PHENYLBENZENESULFONOTHIOATE
(Phenylsulfonyl)phenyl sulfide
Phenyl(phenylsulfonyl) sulfide
benzenesulfonylsulfanylbenzene
S-Phenylbenzenemonothiosulfonate
Benzenethiosulfonic acid S-phenyl
S-Phenyl benzenethiosulfonate 99%
BENZENETHIOSULFONIC ACID S-PHENYL ESTER
Benzenesulfonicacid,thio-,S-phenylester
Benzenesulfonothioic acid, S-phenyl ester
TIANFUCHEM 1212-08-4 BENZENETHIOSULFONIC ACID S-PHENYL ESTER
[EINECS(EC#)]

214-919-1
[Molecular Formula]

C12H10O2S2
[MDL Number]

MFCD00014738
[MOL File]

1212-08-4.mol
[Molecular Weight]

250.34
Chemical PropertiesBack Directory
[Melting point ]

36-53 °C(lit.)
[Boiling point ]

125 °C(Press: 0.01 Torr)
[density ]

1.35±0.1 g/cm3(Predicted)
[Fp ]

>230 °F
[storage temp. ]

-20°C Freezer
[solubility ]

Chloroform (Slightly), DMSO (Slightly), Methanol (Very Slightly)
[form ]

Solid
[color ]

Off-White
[BRN ]

1530592
[InChIKey]

ATKJLMWDXASAJA-UHFFFAOYSA-N
[EPA Substance Registry System]

Benzenesulfonothioic acid, S-phenyl ester (1212-08-4)
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

S-Phenyl Benzenethiosulfonate is an high potency antifungal thiosulfonate that were tested against Aspergillus niger and Aspergillus flavus.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 99, p. 4405, 1977 DOI: 10.1021/ja00455a032
Tetrahedron Letters, 10, p. 1239, 1969
[Purification Methods]

Recrystallise the disulfoxide from EtOH or MeOH. It has also been purified from phenylsulfide impurities by dissolving in CHCl3, washing with aqueous saturated NaHCO3, drying (Na2SO4), filtering, evaporating the filtrate, and the residual oil is passed through a silica gel column (600g) and eluted with hexane/*C6H6 (1L, 4:1, eluting PhSSPh) then *C6H6 (1L) which elutes PhSSO2Ph. [Trost & Massiot J Am Chem Soc 99 4405 1977, Knoevenagel & R.mer Chem Ber 56 215 1923, Beilstein 11 IV 220.]
Spectrum DetailBack Directory
[Spectrum Detail]

BENZENETHIOSULFONIC ACID S-PHENYL ESTER(1212-08-4)IR
BENZENETHIOSULFONIC ACID S-PHENYL ESTER(1212-08-4)Raman
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