ChemicalBook--->CAS DataBase List--->12148-71-9

12148-71-9

12148-71-9 Structure

12148-71-9 Structure
IdentificationBack Directory
[Name]

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
[CAS]

12148-71-9
[Synonyms]

5-cod)]2
[Ir(OMe)(1
[Ir(OMe)(1,5-cod)]2
1,5 cyclooctadiene(μ
-methoxy)iridium(I) dimer
Methoxy(cyclooctadiene)iridium(I) dimer
BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII
Bis(1,5-cyclooctadiene)dimethoxydiiridium
(1,5-Cyclooctadiene)(methoxy)iridium dimer
Bis[(1,5-cyclooctadiene)(methanolato)iridium]
Bis(1,5-cyclooctadiene) di-u-methoxydiiridium
Di-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM
(Cycloocta-1,5-diene)(methoxy)iridium(I) dimer
Bis(cycloocta-1,5-diene) di-u-methoxydiiridium
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I),98%
Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%
Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%
Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
Di-mu-methoxobis(1,5-cyclooctadiene)diiridium (I), min. 98%
IridiuM, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-M-Methoxydi-
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),[Ir(COD)(OMe)]2
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),98% [Ir(COD)(OMe)]2
[EINECS(EC#)]

628-411-6
[Molecular Formula]

C18H30Ir2O2
[MDL Number]

MFCD08459360
[MOL File]

12148-71-9.mol
[Molecular Weight]

662.86
Chemical PropertiesBack Directory
[Appearance]

yellow solid
[Melting point ]

154-177 °C
[storage temp. ]

Room temperature.
[form ]

Powder
[color ]

yellow
[Sensitive ]

Light, Air & Moisture Sensitive
[InChIKey]

WLPGZWOTJGJODI-SXGOCSEPSA-N
Hazard InformationBack Directory
[Chemical Properties]

yellow solid
[Uses]

A catalyst for preparation of heteroaryl fused indole ring systems.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2843909000
Questions And AnswerBack Directory
[Description]

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.
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