ChemicalBook--->CAS DataBase List--->1445085-97-1

1445085-97-1

1445085-97-1 Structure

1445085-97-1 Structure
IdentificationBack Directory
[Name]

Xantphos Palladacycle Gen. 3
[CAS]

1445085-97-1
[Synonyms]

Xantphos Palladacycle Gen. 3
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I
Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II)
Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2-amino-1,1-biphenyl-2-yl)palladium(II)
Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct,[Xantphos Palladacycle Gen. 3]
[Molecular Formula]

C52H45NO4P2PdS
[MDL Number]

MFCD25372941
[MOL File]

1445085-97-1.mol
[Molecular Weight]

949.358
Chemical PropertiesBack Directory
[Melting point ]

164-167 °C (decomposition)
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[form ]

Powder
[color ]

pale yellow
[InChIKey]

JIMOHYWEUIAPAA-UHFFFAOYSA-N
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents.
  2. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose.
  3. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters.
Reactions of 1445085-97-1
Hazard InformationBack Directory
[Uses]

Xantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.
[General Description]

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
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