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148461-14-7

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148461-14-7 Structure

148461-14-7 Structure
IdentificationBack Directory
[Name]

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
[CAS]

148461-14-7
[Synonyms]

Diphenylphosphinophenylmethylethyldihydrooxazole
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%
(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
(4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE
[2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole
(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%
Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)-
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%
(4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.
[Molecular Formula]

C24H24NOP
[MDL Number]

MFCD03427599
[MOL File]

148461-14-7.mol
[Molecular Weight]

373.43
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

85-90 °C
[alpha ]

-44° (c 1.4, CHCl3)
[Boiling point ]

492.7±28.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[pka]

4.31±0.70(Predicted)
[color ]

white
[optical activity]

[α]20/D 48±3°, c = 1% in chloroform
[Sensitive ]

air sensitive
[BRN ]

5879302
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

37/39-26-24/25
[WGK Germany ]

3
[F ]

10-23
[Hazard Note ]

Irritant
[HS Code ]

29349990
Questions and Answers (Q&A)Back Directory
[Reactions]

  1. Chiral ligand used in the asymmetric reduction of highly substituted olefins.
  2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
  3. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
  4. Decarboxylative allylic alkylation.
Reactions of 148461-14-7
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