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171611-11-3

171611-11-3 Structure

171611-11-3 Structure
IdentificationBack Directory
[Name]

Lithium Bis(fluorosulfonyl)imide
[CAS]

171611-11-3
[Synonyms]

LiFSI
LiFSA
ithium Bis(fL
Li[(FSO2)2N]LiFSI
Lithium bisfluorosulfonimide
LithiuM bis(fluorosulfony)iMide
Lithium bis(fluorosulfonyl)imide
Bis(fluorosulfonyl)imide Lithium
bis (fluorosulfonyl) imine lithium
Imidodisulfuryl fluoride lithium salt
LITHIUM BIS (FLUOROSULFONYL) IMIDE/LiFSi
Imidodisulfuryl fluoride lithium salt (LiFSI)
Lithium Bis(fluorosulfonyl)imide ISO 9001:2015 REACH
LiFSI Lithium Bis(fluorosulfonyl)imide
[EINECS(EC#)]

686-526-7
[Molecular Formula]

F2NO4S2.Li
[MDL Number]

MFCD28126786
[MOL File]

171611-11-3.mol
[Molecular Weight]

187.072
Chemical PropertiesBack Directory
[Melting point ]

124-128℃
[density ]

1.052g/cm3 at 25℃
[vapor pressure ]

27.198-31.064Pa at 20-25℃
[storage temp. ]

Inert atmosphere,2-8°C
[Water Solubility ]

Soluble in water
[form ]

Solid
[color ]

White to Almost white
[InChI]

InChI=1S/F2NO4S2.Li/c1-8(4,5)3-9(2,6)7;/q-1;+1
[InChIKey]

HOQSGMWVPMHPSZ-UHFFFAOYSA-N
[SMILES]

[N-](S(=O)(F)=O)S(=O)(F)=O.[Li+]
[LogP]

3 at 20℃ and pH6
[EPA Substance Registry System]

Imidodisulfuryl fluoride, lithium salt (1:1) (171611-11-3)
Safety DataBack Directory
[RIDADR ]

1759
[HS Code ]

2826.19.9000
[HazardClass ]

8
[PackingGroup ]

II
Raw materials And Preparation ProductsBack Directory
[Raw materials]

BIS(FLUOROSULFONYL)IMIDE POTASSIUM SALT-->Lithium tetrafluoroborate-->Dimethyl carbonate
Hazard InformationBack Directory
[Chemical Properties]

White to Almost white powder to crystal with Molecular Crystal Electrolytes with High Lithium Ion Conductivity.
[Characteristics]

Lithium bis(fluorosulfonyl)imide(LiFSI) is a important high-performance electrolyte material in new energy devices such as lithium-ion batteries and supercapacitors. It has the advantages of high stability (no decomposition below 200°C), excellent low temperature performance, good hydrolytic stability and environmental friendliness, etc., as the next generation of lithium hexafluorophosphate electrolyte lithium salt for secondary lithium ion batteries.
[Uses]

Lithium Bis(fluorosulfonyl)imide is a useful research chemical.
[Preparation]

Lithium bis(fluorosulfonyl)imide (LiFSI) was synthesized by a metathesis reaction between KFSI and LiBF4 in DMC in nearly quantitative yield, similar to the preparation of its analogue, lithium (fluorosulfonyl) (pentafluoroethanesulfonyl)imide (LiFPFSI).
DOI: https://doi.org/10.1016/j.jpowsour.2010.12.040
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