ChemicalBook--->CAS DataBase List--->2002-03-1

2002-03-1

2002-03-1 Structure

2002-03-1 Structure
IdentificationBack Directory
[Name]

2-AMINO-5-PHENYL-1 3 4-THIADIAZOLE 96
[CAS]

2002-03-1
[Synonyms]

NSC 677
2-Amino-5-phenyl-1,3,4-thiazole
5-Phenyl-1,3,4-thiadiazole-2-amine
5-Phenyl-2-amino-1,3,4-thiadiazole
1,3,4-thiadiazol-2-amine, 5-phenyl-
2-Amino-5-phenyl-1,3,4-thiadiazole,97%
2-AMino-5-phenyl-1,3,4-thiadiazole 96%
2-AMINO-5-PHENYL-1 3 4-THIADIAZOLE 96
[Molecular Formula]

C8H7N3S
[MDL Number]

MFCD00205278
[MOL File]

2002-03-1.mol
[Molecular Weight]

177.23
Chemical PropertiesBack Directory
[Melting point ]

223-227 °C(lit.)
[Boiling point ]

359.0±25.0 °C(Predicted)
[density ]

1.333±0.06 g/cm3(Predicted)
[pka]

2.90±0.10(Predicted)
[λmax]

267nm(H2SO4 aq.)(lit.)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[HazardClass ]

IRRITANT
Hazard InformationBack Directory
[Uses]

2-Amino-5-phenyl-1,3,4-thiadiazole may be used for the synthesis of 1,3,4-thiadiazole derivatives.
[General Description]

2-Amino-5-phenyl-1,3,4-thiadiazole on condensation with benzaldehyde (SPT), 4-nitrobenzaldehyde (SNT), 4-methoxybenzaldehyde (SMT), 2-hydroxybenzaldehyde (SSTH) or 2-hydroxyacetophenone affords Schiff′s bases. Its molecular geometry and vibrational frequencies have been evaluated using the Hartree-Fock and density functional method (B3LYP). 2-Amino-5-phenyl-1,3,4-thiadiazole has been reported to inhibit the corrosion of mild steel in 0.5M H2SO4 and 1.0M HCl. Corrosion inhibition has been examined using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS).
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