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35836-73-8

35836-73-8 Structure

35836-73-8 Structure
IdentificationBack Directory
[Name]

6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL
[CAS]

35836-73-8
[Synonyms]

(-)-NOPOL
2-((1R,5S)
(1R)-(-)-NOPOL
(1R)-(-)-Nopol,98%
(1R)-(-)-Nopol 98%
Dimethylbicyclohepteneethanol
6,6-DIMETHYL-2-NORPINENE-2-ETHANOL
-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)
6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL
6,6Dimethyllbicyclo(3.1.1)hept-2-ene-2-ethanol
(-)-[(1R)-6,6-Dimethylnorpinane-2-ene]-2-ethanol
(1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol
(1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL
(1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
(1α,5α)-7,7-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol
(1β,5β)-6,6-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol
Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)-
(1β,5β)-2-(2-Hydroxyethyl)-6,6-dimethylbicyclo[3.1.1]hepta-2-ene
(1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol
(-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
[EINECS(EC#)]

252-744-2
[Molecular Formula]

C11H18O
[MDL Number]

MFCD00075187
[MOL File]

35836-73-8.mol
[Molecular Weight]

166.26
Chemical PropertiesBack Directory
[Appearance]

Clear colorless to light yellow liquid
[Boiling point ]

235-236 °C(lit.)
[density ]

0.973 g/mL at 25 °C(lit.)
[vapor pressure ]

2.17Pa at 20℃
[refractive index ]

n20/D 1.493
[Fp ]

210 °F
[storage temp. ]

Refrigerator, under inert atmosphere
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Oil
[pka]

15.03±0.10(Predicted)
[color ]

Clear Colourless
[optical activity]

[α]24/D 37°, neat
[Water Solubility ]

333.5mg/L at 20℃
[Merck ]

14,6683
[BRN ]

3196379
[LogP]

3.09 at 30℃
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to light yellow liquid
[Uses]

(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol.
[Application]

(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.
[Definition]

ChEBI: (-)-Nopol is a monoterpenoid.
[General Description]

(1R)-(-)-Nopol is a chiral terpenol derivative.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[RTECS ]

RC8870000
[HS Code ]

29061900
Spectrum DetailBack Directory
[Spectrum Detail]

6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL(35836-73-8)1HNMR
6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL(35836-73-8)IR
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