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N-Methyl-4-nitroaniline

CAS No.
100-15-2
Chemical Name:
N-Methyl-4-nitroaniline
Synonyms
Nitronaniline;4-nitro-n-methylaniline;Methyl-4-nitroaniline;Intedanib Impurity 10;N-methy-4-nitroanline;N-Methyl-p-nitraniline;Miglinide intermediate;N-METHYL-P-NITROANILINE;N-METHYL-4-NITROANILINE;P-NITRO-N-METHYLANILINE
CBNumber:
CB1387643
Molecular Formula:
C7H8N2O2
Molecular Weight:
152.15
MDL Number:
MFCD00007305
MOL File:
100-15-2.mol
MSDS File:
SDS
Last updated:2024-03-22 11:53:02

N-Methyl-4-nitroaniline Properties

Melting point 149-151 °C(lit.)
Boiling point 294.61°C (rough estimate)
Density 1.2010
vapor density 5.25 (vs air)
refractive index 1.6276 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
pka 0.56±0.12(Predicted)
color Yellow to Very Dark Yellow
Water Solubility <0.1 g/100 mL at 19 ºC
BRN 637920
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey XIFJZJPMHNUGRA-UHFFFAOYSA-N
CAS DataBase Reference 100-15-2(CAS DataBase Reference)
FDA UNII J836WLV9BW
NIST Chemistry Reference Benzenamine, N-methyl-4-nitro-(100-15-2)
EPA Substance Registry System N-Methyl-p-nitroaniline (100-15-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08
Signal word  Danger
Hazard statements  H301+H311+H331-H373-H412
Precautionary statements  P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314
Hazard Codes  T,Xi
Risk Statements  23/24/25-33-36/37/38
Safety Statements  28-36/37/39-45-26
RIDADR  2811
WGK Germany  3
Hazard Note  Highly Toxic/Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29214200
NFPA 704
1
3 0

N-Methyl-4-nitroaniline price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269638 N-Methyl-4-nitroaniline 97% 100-15-2 25g $51.5 2024-03-01 Buy
Sigma-Aldrich 269638 N-Methyl-4-nitroaniline 97% 100-15-2 100g $161 2024-03-01 Buy
Alfa Aesar A15548 N-Methyl-4-nitroaniline, 97% 100-15-2 5g $37.3 2023-06-20 Buy
Alfa Aesar A15548 N-Methyl-4-nitroaniline, 97% 100-15-2 25g $133 2023-06-20 Buy
Alfa Aesar A15548 N-Methyl-4-nitroaniline, 97% 100-15-2 100g $439 2023-06-20 Buy
Product number Packaging Price Buy
269638 25g $51.5 Buy
269638 100g $161 Buy
A15548 5g $37.3 Buy
A15548 25g $133 Buy
A15548 100g $439 Buy

N-Methyl-4-nitroaniline Chemical Properties,Uses,Production

Uses

N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.

Biodegradation

N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.

Chemical Properties

brownish-yellow crystalline powder

Uses

N-Methyl-4-nitroaniline is a versatile reactant used in the synthesis of oxindoles using Pd-catalyzed cyclization of chloroacetanilides.

General Description

Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.

Air & Water Reactions

N-Methyl-4-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

N-Methyl-4-nitroaniline has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.

Fire Hazard

Flash point data for N-Methyl-4-nitroaniline are not available; however, N-Methyl-4-nitroaniline is probably combustible.

Purification Methods

Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.]

Global( 355)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Yingrui Biopharma Co.,Ltd
21-33585366 export01@shyrchem.com CHINA 1320 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Anhui Ruihan Technology Co., Ltd
+8617756083858 daisy@anhuiruihan.com China 994 58
hebei hongtan Biotechnology Co., Ltd
+86-86-1913198-3935 +8617331935328 sales03@chemcn.cn China 951 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9346 55
Shanghai Yingrui Biopharma Co., Ltd.
+86-21-33585366 - 03@ sales03@shyrchem.com CHINA 738 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55

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View Lastest Price from N-Methyl-4-nitroaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-Methyl-4-nitroaniline pictures 2024-04-30 N-Methyl-4-nitroaniline
100-15-2
US $30.00 / kg 1kg 98% 3000kg hebei hongtan Biotechnology Co., Ltd
 N-Methyl-4-nitroaniline pictures 2024-04-30 N-Methyl-4-nitroaniline
100-15-2
US $12.00 / KG 1KG 99% 200mt Jinan Finer Chemical Co., Ltd
N-Methyl-4-nitroaniline pictures 2023-11-20 N-Methyl-4-nitroaniline
100-15-2
US $0.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
4-METHYLAMINONITROBENZENE 1-METHYLAMINO-4-NITROBENZENE Methyl-4-nitroaniline N-Methyl-4-nitroaniline ,99% N-Methyl-4-nitroaniline,97% N-Methyl-4-nitroaniline , 98.0%(GC) Aniline, N-methyl-p-nitro- Benzenamine,N-methyl-4-nitro- n-methyl-4-nitro-benzenamin N-methyl-4-nitro-Benzenamine N-Methyl-N-(4-nitrophenyl)amine N-Methyl-p-nitraniline N-Monomethyl-p-nitroaniline N-METHYL-P-NITROANILINE N-METHYL-4-NITROANILINE P-NITRO-N-METHYLANILINE p-(Methylamino)nitrobenzene N1-methyl-4-nitroaniline N-METHYL-4-NITRO ANILIN Intedanib Impurity 10 N-methy-4-nitroanline N-Methyl-4-nitroaniline> Nintedanib Impurity 130 N-Methyl-4-nitroaniline ISO 9001:2015 REACH N-Methyl-4-nitroanilineolyolefin 4-nitro-n-methylaniline Nitronaniline -Amino-2-methyl-96H-tetrazole Miglinide intermediate 100-15-2 99-52-5 100-15-2 AMINE Organic Building Blocks Nitrogen Compounds C7 Amines Building Blocks Pyridines Building Blocks C7 Chemical Synthesis Materials Science Nitrogen Compounds NLO Chromophores and Intermediates Non-Linear Optical (NLO) Materials Organic and Printed Electronics Organic Building Blocks Photonic and Optical Materials C7Photonic and Optical Materials Amines Nitrogen Compounds NLO Chromophores and Intermediates Non-Linear Optical (NLO) Materials Anilines, Aromatic Amines and Nitro Compounds 100-15-2