ChemicalBook >> CAS DataBase List >>PMK ethyl glycidate
PMK ethyl glycidate
- CAS No.
- 28578-16-7
- Chemical Name:
- PMK ethyl glycidate
- Synonyms
- GLYCIDATE;ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate;Pmk Glycidate Oil;3,4-MDP-2-P intermediate;ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate;2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester;cheap 3,4-MDP-2P ethyl ester;3-(1,3-benzodioxol-5-yl)-2-Methyl-;PMK BMK;New PMK
- CBNumber:
- CB22731285
- Molecular Formula:
- C13H14O5
- Molecular Weight:
- 250.25
- MDL Number:
- MFCD30478653
- MOL File:
- 28578-16-7.mol
Last updated:2024-04-22 16:39:17
| Boiling point | 327.8±42.0 °C(Predicted) |
|---|---|
| Density | 1.302±0.06 g/cm3(Predicted) |
| solubility | DMF: 15 mg/ml; DMSO: 30 mg/ml; Ethanol: 10 mg/ml; PBS (pH 7.2): 1 mg/ml |
| InChI | InChI=1S/C13H14O5/c1-3-15-12(14)13(2)11(18-13)8-4-5-9-10(6-8)17-7-16-9/h4-6,11H,3,7H2,1-2H3 |
| InChIKey | BRILFEZHPXQINW-UHFFFAOYSA-N |
| SMILES | O1C(C2=CC=C3OCOC3=C2)C1(C)C(OCC)=O |
PMK ethyl glycidate price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Cayman Chemical | 21990 | PMK ethyl glycidate ≥98% | 28578-16-7 | 1mg | $73 | 2024-03-01 | Buy |
| Cayman Chemical | 21990 | PMK ethyl glycidate ≥98% | 28578-16-7 | 5mg | $189 | 2024-03-01 | Buy |
| TRC | N900275 | NSC195099 | 28578-16-7 | 10mg | $140 | 2021-12-16 | Buy |
| AK Scientific | 9011CB | Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate | 28578-16-7 | 1mg | $179 | 2021-12-16 | Buy |
| AK Scientific | 9011CB | Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate | 28578-16-7 | 5mg | $309 | 2021-12-16 | Buy |
PMK ethyl glycidate Chemical Properties,Uses,Production
Description
PMK ethyl glycidate is an analytical reference standard categorized as a precursor in the synthesis of methylenedioxy phenethylamines and amphetamines, including 3,4-MDMA. This product is intended for research and forensic applications.
Uses
NSC 195099 can be used as an analytical reference standard.
Application
PMK methyl glycidate is applied as immediate precursors of 3,4-methylenedioxymethamphetamine.
Synthesis
To a solution of piperonal (1, 3.00 g, 19.9 mmol) in CH2Cl2 (100 mL) was added (carbethoxyethylidene)triphenylphosphorane (2,14.5 g, 40.0 mmol), and the reaction mixture was stirred for 24 h at room temperature. The mixture was then concentrated at reduced pressure, and the residue was purified by flash column chromatography on silica gel (hexanes/EtOAc,10:1) to afford olefin 3 (4.45 g, 95%) as a colorless oil: 1H NMR (400 MHz, CDCl3) d 7.58 (s, 1H), 6.92 (d, J = 1.7 Hz, 1H), 6.90 (dd, J = 7.9, 1.7 Hz, 1H), 6.82 (d, J = 8.0 Hz, 1H), 5.97 (s, 2H), 4.24 (q, J = 7.1 Hz, 2H), 2.10 (d, J = 1.6 Hz, 3H),1.33 (t, J = 7.1 Hz, 3H); 13C NMR (100 MHz, CDCl3) d 168.7,147.6, 138.3, 129.9, 126.9, 124.6, 109.5, 108.2, 101.2, 60.7, 14.3,1 4.0; IR (ATR, cm-1): 2981, 2902,1698, 1628, 1502, 1489,1442, 1258, 1224; HRMS (EI) m/z calcd for C13H14O4 (M+) 234.0892, found 234.0895.
Fig The synthetic step of PMK ethyl glycidate
PMK ethyl glycidate Preparation Products And Raw materials
Global( 131)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hong Kong Excellence Biotechnology Co., Ltd. | +86-86-18838029171 +8618126314766 | ada@sh-teruiop.com | China | 893 | 58 |
| Dorne Chemical Technology co. LTD | +86-13583358881 +86-18560316533 | Ethan@dornechem.com | China | 293 | 58 |
| Shanghai Worldyang Chemical Co.,Ltd. | ,+86-21-56795779; +8613651600618 | sales@worldyachem.com | China | 879 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471 | sales@sarms4muscle.com | China | 10523 | 58 |
| Xiamen Wonderful Bio Technology Co., Ltd. | +8613043004613 | Sara@xmwonderfulbio.com | China | 305 | 58 |
| Taiyuan CJ Trading Co., Ltd | +86-18536636121 | anna@lianxuchemical.com | China | 8 | 58 |
| Nanjing Deda New Material Technology Co., Ltd | +8613223293093 | bella@njdeda.com | China | 82 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12470 | 58 |
| Sigma Audley | +86-18336680971 +86-18126314766 | nova@sh-teruiop.com | China | 525 | 58 |
| .GZ HONESTCHEM CO.,LTD | +86-15013270415 | honestchemical@foxmail.com | China | 247 | 58 |
Related articles
- PMK ethyl glycidate: Synthesis and Application
- PMK ethyl glycidate can be used as intermediate in organic synthesis.
- Dec 8，2022
View Lastest Price from PMK ethyl glycidate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-05-10 | PMK ethyl glycidate
28578-16-7
|
US $5.00-1.00 / kg | 1kg | 99.5 | 10 ton per month | Nanjing Deda New Material Technology Co., Ltd | |
 |
2024-05-10 | PMK ethyl glycidate
28578-16-7
|
US $5.00-3.00 / kg | 1kg | 99.8% | 20tons | Nanjing Deda New Material Technology Co., Ltd | |
 |
2024-05-10 | PMK ethyl glycidate
28578-16-7
|
US $5.00-1.00 / kg | 1kg | 99.8% | 20tons per month | Nanjing Deda New Material Technology Co., Ltd |
-
- PMK ethyl glycidate
28578-16-7
- US $5.00-1.00 / kg
- 99.5
- Nanjing Deda New Material Technology Co., Ltd
-
- PMK ethyl glycidate
28578-16-7
- US $5.00-3.00 / kg
- 99.8%
- Nanjing Deda New Material Technology Co., Ltd
-
- PMK ethyl glycidate
28578-16-7
- US $5.00-1.00 / kg
- 99.8%
- Nanjing Deda New Material Technology Co., Ltd
3,4-MDP-2P ethyl ester
Pharmaceutical intermediates 2-Oxiranecarboxylicacid
2-Oxiranecarboxylicacid, 3-(1,3-benzod.../3,4-MDP-2-P intermediate
new p 28578-16-7
3-(1,3-benzod.../3,4-MDP-2-P intermediate
BMK CAS 28578-16-7
Ethyl 3-(1,3-benzodioxol-5-yl)-2-methyl-2-oxiranecarboxylate
Ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate Liquid
PMK BMK
new pmk oil
OXIRANECARBOXYLICACID, 3-(1,3-BENZODIOXOL-5-YL)-2-METHYL-, ETHYL ESTER
/PMK / BMK / PMK ethyl glycidate
BMK PMK Oil
Ethyl Glycidate Oil
99% Purity White crystilline powder ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate
GLYCIDATE oil
PMK ethyl glycidate (PMK powder&oil)
pmk, 3-(1,3-benzodioxol-5-yl)-2-Methyl-
NEW PMK,Pmk,Pmk Glycidate Oil
PMK ethyl glycidate
3,4-MDP-2-P intermediate
2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester
ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate
3-(1,3-benzodioxol-5-yl)-2-Methyl-
cheap 3,4-MDP-2P ethyl ester
Pmk Glycidate Oil
GLYCIDATE
ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate
New PMK
PMK liquid
PMK Oil/ Powder
PMK ethyl glycidate oil
ethyl3-(1,3-benzodioxol-5-yl)-2-methyChemicalbookloxirane-2-carboxylate
pmk oil 28578-16-7
2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester (Related Reference)
benzodioxol
Methyl piperonyl epoxy propionate ethyl ester
PMK ethyl glycidate PMK Powder PMK Oil
PMK Oil/ PMK Glycidate
ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carb
PMK ethyl glycidate powder
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