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Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Tris(dibenzylideneacetone)dipalladium-chloroform adduct structure

CAS No.: 52522-40-4

Chemical Name:: Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Synonyms: Pd2dba3.CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT;Pd2(bda)3 CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM;Tris(dibenzylideneacetone)dipalladium(0)-chloroform;chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium;Tris DBA;adium-chL;oroform adduct

CBNumber:: CB2298434

Molecular Formula:: C52H31Cl3O3Pd2

Molecular Weight:: 1023.01

MDL Number:: MFCD00075479

MOL File:: 52522-40-4.mol

Last updated:2023-04-23 16:37:41

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Tris(dibenzylideneacetone)dipalladium-chloroform adduct Properties

Melting point	131-135 °C(lit.)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Crystalline Powder
color	Purple to black
Water Solubility	Soluble in organic solvents. Insoluble in water.
Sensitive	Air & Moisture Sensitive
InChIKey	NLYJPAJWGANOKG-CXKPDERJSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS08

Signal word

Warning

Hazard statements

H302-H315-H351

Precautionary statements

P201-P202-P264-P301+P312-P302+P352-P308+P313

Hazard Codes

Xn,Xi

Risk Statements

22-38-40-48/20/22-36/37/38

Safety Statements

36/37-37/39-26

WGK Germany

TSCA

HS Code

28439000

NFPA 704

	1
2		0

Tris(dibenzylideneacetone)dipalladium-chloroform adduct price More Price(40)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	366315	Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct	52522-40-4	250mg	$49.1	2024-03-01	Buy
Sigma-Aldrich	366315	Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct	52522-40-4	1g	$178	2024-03-01	Buy
Alfa Aesar	044969	Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%	52522-40-4	1g	$109	2024-03-01	Buy
Alfa Aesar	044969	Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%	52522-40-4	5g	$396.65	2024-03-01	Buy
Strem Chemicals	46-3010	Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct	52522-40-4	500mg	$67	2024-03-01	Buy

Product number	Packaging	Price	Buy
366315	250mg	$49.1	Buy
366315	1g	$178	Buy
044969	1g	$109	Buy
044969	5g	$396.65	Buy
46-3010	500mg	$67	Buy

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties,Uses,Production

Reaction

Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.
Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2‘biphenylylene ditriflates.
Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.
Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.
Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.
Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.
Palladium catalyst for asymmetric addition of oxindoles and allenes.
Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.
Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.
Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.

Chemical Properties

purple to black crystalline powder

Uses

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct is a catalyst that is used in the preparation of anticancer activity of amino vinylindoles via palladium catalyzed coupling of hydrazone, haloindoles and amines.

Uses

suzuki reaction

Application

Tris(dibenzylideneacetone)dipalladium-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
As cyclization catalyst.
As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

General Description

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd₂dba₃·CHCl₃) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst.

Biological Activity

N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials

Raw materials

Sodium acetate Acetonitrile Ethanol tert-Butyl methyl ether Acetone

Toluene Chloroform Benzaldehyde Diethyl ether Ammonium chloride

Palladium chloride Dichloromethane Methanol Sodium hydroxide

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Preparation Products

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Suppliers

Global( 287)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	+undefined-027-81388558 +undefined086-1878077615	huahandingcheng@sina.com	China	342	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15932	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
AB PharmaTech,LLC	323-480-4688		United States	989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	sales@dolonchem.com	CHINA	2972	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58

Supplier	Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
AB PharmaTech,LLC	55
career henan chemical co	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Accela ChemBio Inc.	58

View Lastest Price from Tris(dibenzylideneacetone)dipalladium-chloroform adduct manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-01-23	Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4	US $0.00 / KG	1KG	98.00%	100KG /month	Shanghai Daken Advanced Materials Co.,Ltd
2021-06-11	Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4	US $10.00-10.00 / g	1g	0.98	50KG	Wuhan LPBchem Technology Co.,Ltd
2020-11-16	Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4	US $20.00 / KG	1KG	99%	10000KG	Longyan Tianhua Biological Technology Co., Ltd

Tris(dibenzylideneacetone)dipalladium-chloroform adduct
52522-40-4
US $0.00 / KG
98.00%
Shanghai Daken Advanced Materials Co.,Ltd

Tris(dibenzylideneacetone)dipalladium-chloroform adduct
52522-40-4
US $10.00-10.00 / g
0.98
Wuhan LPBchem Technology Co.,Ltd

Tris(dibenzylideneacetone)dipalladium-chloroform adduct
52522-40-4
US $20.00 / KG
99%
Longyan Tianhua Biological Technology Co., Ltd

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Spectrum

Tris(dibenzylideneacetone)dipalladium-chloroform adduct(52522-40-4)¹HNMR Tris(dibenzylideneacetone)dipalladium-chloroform adduct(52522-40-4)IR

52522-40-4(Tris(dibenzylideneacetone)dipalladium-chloroform adduct)Related Search:

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Benzalacetone BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Benzyltriethylammonium chloride Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium

TRIS(DIMETHYLAMINO)ANTIMONY TRIS(DIMETHYLAMINO)SILANE Tris(dibenzylideneacetone)dipalladium Tris(triphenylphosphine)rhodiu Tris(dimethylaminomethyl)phenol

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TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0) TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX Dipalladiumtris(dibenzylideneacetone) chloroform adduct TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+% Tris(dibenylideneacetone)dipalladium-chloroform Tris (dibenzylidene acetone)di palladiuM(O)-chloroforM addict Tris DBA chloroform adduct Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6% Tris(dibenzylideneacetone)dipalladium-chloroform adduct,97% Tris-(dibenzylideneacetone)-dipalladium(O)-chloroform adduct Tris(Dibenzylideneacetone)Dipalladium(0), Complex With Chloroform, Pd Tris DBA Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct [Pd > 20.2%] Tris(dibenzylideneacetone)dipalladiuM-chloroforM adduct, 97% 1GR Tris(dibenzylideneacetone)dipalladiuM (0) chloroforM adduct, Pd2(dba)3·CHCl3 Tris(Dibenzylideneacetone)DipalladiuM- ChloroforM AdduCL 2,2'',3',6,6'',7'-hexaphenyldispiro[1-palladatricyclo[3.1.0.0^{1,3}]hexane-1,2'-[1,2]dipalladatricyclo[4.1.0.0^{2,4}]heptane-1',1''-[1]palladatricyclo[3.1.0.0^{1,3}]hexane]-2,2'',3',5,5'',6'-hexaene-4,4'',5'-trione adium-chL oroform adduct DIPALLADIUM(0)TRIS(DIBENZYLI tris(dibenzylideneacetone)(chloroform)-di-p Tris(dibenzylideneacetone)dipalladium-chloroform a Tris(dibenzylideneacetone)dipalladium chloroform adduct 98% (1E,4E)-1,5-diphenyl-3-penta-1,4-dienone Tris(dibenzylideneacetone)dipalladium-chloroform adduct ISO 9001：2015 REACH Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4 TRIS (DIBENZYLIDENEACETONE) DIPALLADIUM CHLOROFORM ADDUCT For Synthesis TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium Tris(dibenzylideneacetone)dipalladium(0)-chloroform Pd2dba3.CHCl3 Pd2(bda)3 CHCl3 Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1) (9CI, ACI) Trismu-(1,2-eta:4,5-eta)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-palladium compd. with trichloromethane (1:1) 52522-40-4 52552-40-4 C52H43Cl3O3Pd2 C51H42O3Pd2CHCl3 Pd2C17H14O3CHCl3 C6H5CHCHCOCHCHC6H53Pd2CHCl3 C52Cl3H43O3Pd2 C35H29Cl3O2Pd C6H5CHCHCOCHCHC6H53Pd2稢HCl3 3C17H14OCHCl32Pd Catalysis and Inorganic Chemistry New Products for Chemical Synthesis May/June 2007 Homogeneous Pd Catalysts organometallic complexes Metal Compounds