ChemicalBook >> CAS DataBase List >>(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline
- CAS No.
- 20316-18-1
- Chemical Name:
- (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline
- Synonyms
- Lycodine;(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline;1H-5,10b-Propano-1,7-phenanthroline, 2,3,4,4a,5,6-hexahydro-12-methyl-, (4aR,5S,10bR,12R)-
- CBNumber:
- CB32389409
- Molecular Formula:
- C16H22N2
- Molecular Weight:
- 242.36
- MDL Number:
- MOL File:
- 20316-18-1.mol
Last updated:2023-05-04 17:34:35
| Melting point | 118-119° |
|---|---|
| alpha | D -10° (c = 1.01 in ethanol) |
| pka | 3.97, 8.08(at 25℃) |
| FDA UNII | 7K0NX2M1NN |
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Chemical Properties,Uses,Production
Description
One of the numerous alkaloids obtained from the various Lycopodium species, this base has been found in L. annotinurn L. and L. fawcettii. It forms colourless crystals and has [α]D - 10° ± 2° (c 1.01, EtOH). One of the nitrogen atoms is present in a pyridine ring, the other being in the form of an imino group. The picrate is obtained as prisms from MeOH and has m.p. 229-233°C.
Definition
ChEBI: Lycodine is a phenanthrol.
References
Anet, Eves., Can. J. Chern., 36,902 (1958)
Anet, Rao., Tetrahedron Lett., No. 20, 9 (1960)
Burnell et al., Can. J. Chern., 41, 3091 (1963)
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Preparation Products And Raw materials
Raw materials
Preparation Products
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Suppliers
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(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline
Lycodine
1H-5,10b-Propano-1,7-phenanthroline, 2,3,4,4a,5,6-hexahydro-12-methyl-, (4aR,5S,10bR,12R)-
20316-18-1