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1-(1-Methyl-2-piperidinyl)acetone

CAS No.
18747-42-7
Chemical Name:
1-(1-Methyl-2-piperidinyl)acetone
Synonyms
Methylisopunicine;Methylisopelletierine;N-Methylisopelletierine;(+/-)-1-Methylpelletierine;1-(1-Methyl-2-piperidinyl)acetone;1-(1-Methyl-2-piperidinyl)-2-propanone;1-(1-methylpiperidin-2-yl)propan-2-one;2-Propanone, 1-(1-methyl-2-piperidinyl)-
CBNumber:
CB41237281
Molecular Formula:
C9H17NO
Molecular Weight:
155.24
MDL Number:
MFCD01672923
MOL File:
18747-42-7.mol
Last updated:2023-05-04 17:34:35

1-(1-Methyl-2-piperidinyl)acetone Properties

Boiling point 217℃
Density 0.920
refractive index 1.4674
Flash point 67℃
storage temp. Refrigerator
solubility Chloroform (Slightly), DMSO (Slightly), Ethanol (Slightly)
form Oil
pka 9.53±0.10(Predicted)
color Orange to Very Dark Orange
FDA UNII 7A42OMR1WL

1-(1-Methyl-2-piperidinyl)acetone price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M223080 Methylisopelletierine 18747-42-7 50mg $175 2021-12-16 Buy
American Custom Chemicals Corporation PXT0005157 METHYLISOPELLETIERINE 95.00% 18747-42-7 5MG $498.04 2021-12-16 Buy
Crysdot CD32002150 Methylisopelletierine 95+% 18747-42-7 5mg $590 2021-12-16 Buy
Arctom AS365294 Methylisopelletierine ≥98% 18747-42-7 5mg $226 2021-12-16 Buy
Arctom CFN99865 Methylisopelletierine 18747-42-7 5mg $373 2021-12-16 Buy
Product number Packaging Price Buy
M223080 50mg $175 Buy
PXT0005157 5MG $498.04 Buy
CD32002150 5mg $590 Buy
AS365294 5mg $226 Buy
CFN99865 5mg $373 Buy

1-(1-Methyl-2-piperidinyl)acetone Chemical Properties,Uses,Production

Description

This alkaloid occurs in the bark of Punica Granatum L. and was first isolated by Piccinini under the name of isomethylpelletierine. The base is an oily liquid with an alkaline reaction, miscible with H20 and optically inactive. The hydrochloride has m.p. lS6°C; the hydrobromide, m.p. lSI-2°C; the aurichloride forms rosettes of orange-yellow needles, m.p. lIS-7°C and the picrate has m.p. lS7-8°C. The alkaloid may be resolved into its optically active components. (+)-methy1isopelletierine (+)-hydrogen tartrate has m.p. 133-4°C; [α]20D + 22.7°, the corresponding figures for the antipode being m.p. 132-40c;~aH)S - 20.83° while the two hydrochlorides have [α]18D + 11.08° and - 10.64° respectively.
The base gives a semicarbazone as colourless crystals, m.p. 169°C; an oxime, b.p. 1600C/12 mm and a hydrazone, b.p. lS4-SoC/29 mm. The methiodide yields cubic crystals, m.p. lS6°C. Oxidation with chromic acid in H2S04 furnishes N-methylpiperidine-2-carboxylic acid.

Definition

ChEBI: N-Methylpelletierine is a citraconoyl group.

References

Piccinini., Gazzetta, 29, ii, 311 (1899)
Hess et al., Ber., SO, 344, 1386 (1917)
Hess et al., ibid, 51,741 (1918)
Hess et al., ibid, 52, 964, 100S (1919)

1-(1-Methyl-2-piperidinyl)acetone Preparation Products And Raw materials

Raw materials

Preparation Products

1-(1-Methyl-2-piperidinyl)acetone Suppliers

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ALB Technology Limited 702-983-3769 sales@albtechnology.com United States 2993 55
1-(1-Methyl-2-piperidinyl)acetone Methylisopelletierine (+/-)-1-Methylpelletierine 1-(1-Methyl-2-piperidinyl)-2-propanone Methylisopunicine N-Methylisopelletierine 1-(1-methylpiperidin-2-yl)propan-2-one 2-Propanone, 1-(1-methyl-2-piperidinyl)- 18747-42-7