ChemicalBook >> CAS DataBase List >>ethyl 4,4,4-trifluorobut-2-enoate

ethyl 4,4,4-trifluorobut-2-enoate

CAS No.
406-10-0
Chemical Name:
ethyl 4,4,4-trifluorobut-2-enoate
Synonyms
ethyl 4,4,4-trifluorobut-2-enoate;4,4,4-trifluoro-2-Butenoic acid ethyl ester;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
CBNumber:
CB41551282
Molecular Formula:
C6H7F3O2
Molecular Weight:
168.11
MDL Number:
MFCD00009903
MOL File:
406-10-0.mol
MSDS File:
SDS
Last updated:2022-11-11 11:01:00

ethyl 4,4,4-trifluorobut-2-enoate Properties

Density 1.125 g/mL at 25 °C(lit.)
refractive index n20/D 1.3601(lit.)
Flash point 26°C
Boiling point 114-115°C(lit.)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H319-H335
Precautionary statements  P210-P305+P351+P338
RIDADR  UN 3272 3 / PGIII
WGK Germany  3

ethyl 4,4,4-trifluorobut-2-enoate price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269697 Ethyl 4,4,4-trifluorocrotonate 98% 406-10-0 5g $77.2 2024-03-01 Buy
Product number Packaging Price Buy
269697 5g $77.2 Buy

ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties,Uses,Production

Uses

Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.

General Description

The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.

ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials

Raw materials

Preparation Products

ethyl 4,4,4-trifluorobut-2-enoate Suppliers

Global( 18)Suppliers
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Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34571 58
Anichem Inc. 0512-69369885 sales@anichem.com.cn China 497 55
Shanghai Tombiopharma Chemical Co. Ltd. 13391076197 tombiopharma@163.com China 4992 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Zhengzhou Huiju Chemical Co., Ltd. 0371-55900031 18137872243 2853979815@qq.com China 10016 55
Nanjing Chemedicine BioTech Co., Ltd. 15722927296 71139532@qq.com China 427 58
TCI (Shanghai) Chemical Trading Co., Ltd. 021-61109150 sales@tcisct.com China 31163 58
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 63720 58
Aikon International Limited 18626450290 yftan@aikonchem.com China 10718 58
Hangzhou Mingma Technology Co., LTD 17621758100 xinming1991@126.com China 109 58
ethyl 4,4,4-trifluorobut-2-enoate 2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester 4,4,4-trifluoro-2-Butenoic acid ethyl ester 406-10-0