ChemicalBook >> CAS DataBase List >>2-Methoxypyrazine

2-Methoxypyrazine

CAS No.
3149-28-8
Chemical Name:
2-Methoxypyrazine
Synonyms
METHOXYPYRAZINE;Pyrazine, methoxy-;FEMA 3302;methoxy-pyrazin;FEMA NUMBER 3302;2-METHOXYPYRAZINE;Methoxypyrazine,98%;METHOXYPYRAZINE, 2-;Pyrazine, 2-Methoxy-;2-Methoxypyrazine>
CBNumber:
CB4202646
Molecular Formula:
C5H6N2O
Molecular Weight:
110.11
MDL Number:
MFCD00006126
MOL File:
3149-28-8.mol
MSDS File:
SDS
Last updated:2024-04-29 14:28:21

2-Methoxypyrazine Properties

Boiling point 60-61 °C/29 mmHg (lit.)
Density 1.14 g/mL at 25 °C (lit.)
FEMA 3302 | METHOXYPYRAZINE
refractive index n20/D 1.509(lit.)
Flash point 114 °F
storage temp. Sealed in dry,Room Temperature
pka 0.53±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Specific Gravity 1.140
Odor at 1.00 % in dipropylene glycol. sweet nutty cocoa
Odor Type chocolate
JECFA Number 787
BRN 2241
LogP 0.75
CAS DataBase Reference 3149-28-8(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) METHOXYPYRAZINE
EWG's Food Scores 1
FDA UNII RYD35T7F4T
NIST Chemistry Reference Pyrazine, methoxy-(3149-28-8)
EPA Substance Registry System Pyrazine, methoxy- (3149-28-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H226-H302-H315-H318-H335
Precautionary statements  P261-P280-P305+P351+P338
Hazard Codes  Xn
Risk Statements  10-22-37/38-41
Safety Statements  16-26-39
RIDADR  UN 1993 3/PG 3
WGK Germany  3
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29339990
NFPA 704
2
2 0

2-Methoxypyrazine price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W330205 2-Methoxypyrazine ≥99%, FCC, FG 3149-28-8 1kg $1120 2023-01-07 Buy
Sigma-Aldrich 291420 2-Methoxypyrazine 95% 3149-28-8 5g $33 2023-01-07 Buy
Sigma-Aldrich W330205 2-Methoxypyrazine ≥99%, FCC, FG 3149-28-8 sample-k $53.8 2022-05-15 Buy
Sigma-Aldrich W330205 2-Methoxypyrazine ≥99%, FCC, FG 3149-28-8 25g $102 2022-05-15 Buy
Sigma-Aldrich W330205 2-Methoxypyrazine ≥99%, FCC, FG 3149-28-8 100g $166 2022-05-15 Buy
Product number Packaging Price Buy
W330205 1kg $1120 Buy
291420 5g $33 Buy
W330205 sample-k $53.8 Buy
W330205 25g $102 Buy
W330205 100g $166 Buy

2-Methoxypyrazine Chemical Properties,Uses,Production

Description

2-methoxypyrazine is a kind of pyrazine derivative. It emits a kernels and cocoa-like aroma. It is a commonly used daily, food flavoring agent. It has many kinds of flavoring derivatives such as 3-Isobutyl-2-methoxypyrazine, 3-sec-butyl-2-methoxypyrazine, 3-alkyl-2-methoxypyrazines and 3-isopropyl-2-methoxypyrazine. There derivatives could be found in wine and many kinds of fruits such as berry and grapes.

References

Murray, K. E., J. Shipton, and F. B. Whitfield. "2-methoxypyrazines and the flavour of green peas (Pisum sativum). " Chemistry & Industry 27.14(1970):897-898.
Hashizume, Katsumi, and Takashi Samuta. "Grape maturity and light exposure affect berry methoxypyrazine concentration." American Journal of Enology and Viticulture 50.2 (1999): 194-198.
Hartmann, Peter J., Harold M. McNair, and Bruce W. Zoecklein. "Measurement of 3-alkyl-2-methoxypyrazine by headspace solid-phase microextraction in spiked model wines." American Journal of Enology and Viticulture 53.4 (2002): 285-288.
HASHiZUME, Katsumi, and Norihiko Umeda. "Methoxypyrazine content of Japanese red wines." Bioscience, biotechnology, and biochemistry 60.5 (1996): 802-805.
Lacey, Michael J., et al. "Methoxypyrazines in Sauvignon blanc grapes and wines." American Journal of Enology and Viticulture 42.2 (1991): 103-108.

Description

Methoxypyrazine has an odor threshold of 700 ppb in water. Methoxypyrazine may be prepared from 2-hydroxypyrazine by various routes.

Chemical Properties

Colorless liquid

Chemical Properties

Methoxypyrazine has a sweet, nutty, cocoa odor. Methoxypyrazine contributes a distinctive “green, capsicum (bell pepper), herbaceous and earthy” aroma that is quite characteristic of certain wines, such as sauvignon blanc and cabernet sauvignon.

Occurrence

Present at ultra-trace levels in sauvignon blanc and cabernet sauvignon grapes and wine. Methoxypyrazine contributes a distinctive wine aroma, even at low parts per trillion levels. Also reported found in cooked beef, cocoa, malt and krill.

Preparation

From 2-hydroxypyrazine by various routes.

Definition

ChEBI: Methoxypyrazine is an aromatic ether and a member of pyrazines.

Aroma threshold values

700 ppb in water

Safety Profile

Skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx.

14508-49-7
124-41-4
3149-28-8
Synthesis of 2-Methoxypyrazine from 2-Chloropyrazine and Sodium Methoxide
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View Lastest Price from 2-Methoxypyrazine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methoxypyrazine pictures 2024-04-29 2-Methoxypyrazine
3149-28-8
US $5.00 / kg 1kg 99.92% 50000tons Ouhuang Engineering Materials (Hubei) Co., Ltd
2-Methoxypyrazine pictures 2024-04-23 2-Methoxypyrazine
3149-28-8
US $50.00 / kg 1kg 99.10% 50000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
2-Methoxypyrazine pictures 2023-09-14 2-Methoxypyrazine
3149-28-8
US $100.00 / drum 1drum 99 5000 Hebei Fengqiang Trading Co., LTD
  • 2-Methoxypyrazine pictures
  • 2-Methoxypyrazine
    3149-28-8
  • US $5.00 / kg
  • 99.92%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • 2-Methoxypyrazine pictures
  • 2-Methoxypyrazine
    3149-28-8
  • US $50.00 / kg
  • 99.10%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
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