Chloro(1,5-cyclooctadiene)iridium(I) dimer
- CAS No.
- 12112-67-3
- Chemical Name:
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- Synonyms
- BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE;[Ir(1,5-cod)Cl]2;IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER;Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2);Chloro(1;IRIDIUM COD CHLORIDE;Chloro(1,5-cyclooctadiene;ooctadiene)diiridium(I) dichL;IRIDIUM CHLORO-1,5-CYCLOOCTADIENE;IRIDIUM I CYCLOOCTADIENE CHLORIDE
- CBNumber:
- CB4212508
- Molecular Formula:
- C16H24Cl2Ir2
- Molecular Weight:
- 671.7
- MDL Number:
- MFCD00012414
- MOL File:
- 12112-67-3.mol
- MSDS File:
- SDS
Melting point | 205 °C (dec.)(lit.) |
---|---|
storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Powder |
color | red to orange |
Water Solubility | insoluble |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
InChIKey | XHOSESNLNGITPM-XRGHXPOKSA-L |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P305+P351+P338-P280a-P304+P340-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-37/39 | |||||||||
WGK Germany | 3 | |||||||||
F | 10 | |||||||||
TSCA | No | |||||||||
HS Code | 28439000 | |||||||||
NFPA 704 |
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Chloro(1,5-cyclooctadiene)iridium(I) dimer price More Price(49)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 683094 | Bis(1,5-cyclooctadiene)diiridium(I) dichloride 97% | 12112-67-3 | 500mg | $164 | 2024-03-01 | Buy |
Sigma-Aldrich | 683094 | Bis(1,5-cyclooctadiene)diiridium(I) dichloride 97% | 12112-67-3 | 2g | $417 | 2024-03-01 | Buy |
TCI Chemical | C1807 | Chloro(1,5-cyclooctadiene)iridium(I) Dimer >93.0%(T) | 12112-67-3 | 1g | $581 | 2024-03-01 | Buy |
TCI Chemical | C1807 | Chloro(1,5-cyclooctadiene)iridium(I) Dimer >93.0%(T) | 12112-67-3 | 250mg | $224 | 2024-03-01 | Buy |
Alfa Aesar | 012749 | Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% | 12112-67-3 | 0.25g | $105 | 2023-06-20 | Buy |
Chloro(1,5-cyclooctadiene)iridium(I) dimer Chemical Properties,Uses,Production
Reactions
1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
2. Precursor to catalyst for enantioselective reduction of imines.
3. Precursor to catalyst for allylic alkylation.
4. Precursor to catalyst for allylic amination and etherification.
5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
6. Ir-catalyzed addition of acid chlorides to terminal alkynes.
7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.
8. Enantioselective [2+2] cycloaddition.
9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes.
10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.
11. Transfer hydrogenative C-C coupling
Chemical Properties
red-orange solid
Uses
Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.
Chloro(1,5-cyclooctadiene)iridium(I) dimer Preparation Products And Raw materials
Raw materials
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Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32686 | 60 |
AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
View Lastest Price from Chloro(1,5-cyclooctadiene)iridium(I) dimer manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-02-08 | Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
|
US $0.00 / G | 10G | 98%min | 30kg/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2022-09-24 | Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
|
US $0.00 / kg | 1kg | 99% | 1000kg | henan kanbei chemical co.,ltd | ||
2021-07-13 | Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
- US $0.00 / G
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
- US $0.00 / kg
- 99%
- henan kanbei chemical co.,ltd
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
12112-67-3
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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