ChemicalBook >> CAS DataBase List >>t-BuXphos Palladacycle Gen. 4

t-BuXphos Palladacycle Gen. 4

CAS No.
1599466-89-3
Chemical Name:
t-BuXphos Palladacycle Gen. 4
Synonyms
t-BuXphos Pd G4;T-BUTYLXPHOS PD G4;T-BUTYLXPHOS PD G4E;[T-BUXPHOS PALLADACYCLE GEN. 4];t-BuXphos Palladacycle Gen. 4 ISO 9001:2015 REACH;Ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl...;Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II);Methanesulfonato(2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);DITERT-BUTYL-[2-[2,4,6-TRI(PROPAN-2-YL)PHENYL]PHENYL]PHOSPHANE;DICHLOROMETHANE;METHANESULFONATE;N-METHYL-2-PHENYLANILINE;PALLADIUM(2+)
CBNumber:
CB43159040
Molecular Formula:
C44H62Cl2NO3PPdS
Molecular Weight:
893.332741
MDL Number:
MFCD31654434
MOL File:
1599466-89-3.mol
Last updated:2023-05-04 15:16:47

t-BuXphos Palladacycle Gen. 4 Properties

form Powder
color off-white to gray

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

t-BuXphos Palladacycle Gen. 4 price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 46-0330 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4] 1599466-89-3 250mg $110 2024-03-01 Buy
Strem Chemicals 46-0330 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4] 1599466-89-3 1g $328 2024-03-01 Buy
Strem Chemicals 46-0330 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4] 1599466-89-3 5g $1309 2024-03-01 Buy
Ambeed A627722 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct 98% 1599466-89-3 5g $632 2021-12-16 Buy
Ambeed A627722 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct 98% 1599466-89-3 1g $168 2021-12-16 Buy
Product number Packaging Price Buy
46-0330 250mg $110 Buy
46-0330 1g $328 Buy
46-0330 5g $1309 Buy
A627722 5g $632 Buy
A627722 1g $168 Buy

t-BuXphos Palladacycle Gen. 4 Chemical Properties,Uses,Production

Reaction

Alternative N-methyl catalyst for mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media. Reactions of 1599466-89-3

Uses

t-BuXphos Palladacycle Gen. 4 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

Forms and nomenclature

Off-white to gray powder

1581285-85-9
564483-19-8
313368-92-2
Synthesis of t-BuXphos Palladacycle Gen. 4 from (2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer and 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

t-BuXphos Palladacycle Gen. 4 Preparation Products And Raw materials

Global( 71)Suppliers
Supplier Tel Email Country ProdList Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
+undefined-027-81388558 +undefined086-1878077615 huahandingcheng@sina.com China 342 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15957 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.
+86-0532-8699-9256 +8615254267723 kaley@cnfdevelop.com China 1410 58
Wuhan LPBchem Technology Co.,Ltd
+86-027-63498399 15071314134 LPBchem@163.com CHINA 57 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 6709 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 28455 58
Baoji Guokang Healthchem co.,ltd
+8615604608665 15604608665 dominicguo@gk-bio.com CHINA 9427 58

Related articles

View Lastest Price from t-BuXphos Palladacycle Gen. 4 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
t-BuXphos Palladacycle Gen. 4  pictures 2022-07-25 t-BuXphos Palladacycle Gen. 4
1599466-89-3
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4 pictures 2021-06-11 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4
1599466-89-3
US $10.00-10.00 / g 1g 0.98 50kg Wuhan LPBchem Technology Co.,Ltd
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min [T-BUXPHOS PALLADACYCLE GEN. 4] Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[T-BUXPHOSPALLADACYCLEGEN.4] Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II) Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, [t-BuXphos Palladacycle Gen. 4] T-BUTYLXPHOS PD G4E Ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane DITERT-BUTYL-[2-[2,4,6-TRI(PROPAN-2-YL)PHENYL]PHENYL]PHOSPHANE;DICHLOROMETHANE;METHANESULFONATE;N-METHYL-2-PHENYLANILINE;PALLADIUM(2+) T-BUTYLXPHOS PD G4 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4 t-BuXphos Palladacycle Gen. 4 ISO 9001:2015 REACH Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),t-BuXphos Palladacycle Gen. 4 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl... t-BuBrettPhos Pd G3 / Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) t-BuXphos Pd G4 Methanesulfonato(2-DI-t-butylphosphino-2',4',6'-tri-I-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-YL)palladium(II) (T-buxphos PD g4) Methanesulfonato(2-di-t-butylphosphino-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-methylamino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct Methanesulfonato(2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) 1599466-89-3 C43H60NO3PPdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd