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Bis(benzonitrile)palladium chloride

Bis(benzonitrile)palladium chloride Structure
Bis(benzonitrile)palladium chloride structure
CAS No.
14220-64-5
Chemical Name:
Bis(benzonitrile)palladium chloride
Synonyms
Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Dichlorobis(benzonitrile)palladium;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladiuM(II);DICHLOROBIS(BENZONITRILE)PALLADIUM(II);Bis(benzonitriL;Bis(benzonitrile;Bis (benzonitrile) palladiuM
CBNumber:
CB4339461
Molecular Formula:
C14H10Cl2N2Pd
Molecular Weight:
383.57
MDL Number:
MFCD00013123
MOL File:
14220-64-5.mol
Last updated:2023-07-26 16:38:33
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Bis(benzonitrile)palladium chloride Properties

Melting point 131 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Soluble in acetone, chloroform
form Crystalline Powder
color Orange to brown
Water Solubility insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 3981730
Exposure limits NIOSH: IDLH 25 mg/m3
InChI InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference 14220-64-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS07
Signal word  Danger
Hazard statements  H301+H311+H331-H315-H319-H302-H312-H332
Precautionary statements  P280h-P301+P312a-P304+P340-P321-P501a-P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501
Hazard Codes  Xn
Risk Statements  20/21-23/24/25
Safety Statements  22-24/25-23-45-36/37-27-20-9-4
RIDADR  UN3439
WGK Germany  3
F  9
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  28439090
NFPA 704
0
1 0

Bis(benzonitrile)palladium chloride price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 223689 Bis(benzonitrile)palladium(II) chloride 95% 14220-64-5 1g $87.6 2024-03-01 Buy
Sigma-Aldrich 223689 Bis(benzonitrile)palladium(II) chloride 95% 14220-64-5 10g $806 2024-03-01 Buy
TCI Chemical B1668 Bis(benzonitrile)palladium(II) Dichloride >98.0%(T) 14220-64-5 1g $199 2024-03-01 Buy
TCI Chemical B1668 Bis(benzonitrile)palladium(II) Dichloride >98.0%(T) 14220-64-5 5g $747 2024-03-01 Buy
Alfa Aesar 010006 trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1% 14220-64-5 1g $128.65 2024-03-01 Buy
Product number Packaging Price Buy
223689 1g $87.6 Buy
223689 10g $806 Buy
B1668 1g $199 Buy
B1668 5g $747 Buy
010006 1g $128.65 Buy

Bis(benzonitrile)palladium chloride Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
Reactions of 14220-64-5_1
Reactions of 14220-64-5_2

Chemical Properties

yellow powder

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

suzuki reaction

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Raw materials

Toluene Palladium chloride Benzonitrile

Preparation Products

Chlorodimethylphenylsilane 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Bis(tricyclohexylphosphine)palladium(II) Dichloride

Bis(benzonitrile)palladium chloride Suppliers

Global( 361)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21637 55
Hangzhou FandaChem Co.,Ltd. 		+8615858145714 FandaChem@Gmail.com China 9215 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32951 60
AB PharmaTech,LLC 		323-480-4688 sales@acrospharmatech.com United States 989 55
Zjartschem 		+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29885 58
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 sales@dolonchem.com CHINA 2972 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 17159 58
Supplier Advantage
Shaoxin Catsyn Co., Ltd.
58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
AB PharmaTech,LLC 		55
Zjartschem 		58
career henan chemical co 		58
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Accela ChemBio Inc. 		58

View Lastest Price from Bis(benzonitrile)palladium chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(benzonitrile)palladium(II)chloride pictures 2024-11-05 Bis(benzonitrile)palladium(II)chloride
14220-64-5
 US $0.00 / KG 1KG 98.00% 100KG /month Shanghai Daken Advanced Materials Co.,Ltd
Bis(benzonitrile)palladium chloride pictures 2023-01-31 Bis(benzonitrile)palladium chloride
14220-64-5
 US $100.00 / kg 1kg 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Bis(benzonitrile)palladium chloride pictures 2022-09-24 Bis(benzonitrile)palladium chloride
14220-64-5
 US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd

Bis(benzonitrile)palladium chloride Spectrum

Bis(benzonitrile)palladium chloride(14220-64-5)1HNMRBis(benzonitrile)palladium chloride(14220-64-5)IR1Bis(benzonitrile)palladium chloride(14220-64-5)IR2Bis(benzonitrile)palladium chloride(14220-64-5)Raman

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TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2 trans-Bis(benzonitrile)palladiuM chloride Dichlorobis(benzonitrile)palladium(Ⅱ) Benzonitrile, palladium complex Bis(phenylnitrile)dichloropalladium Dibenzonitrilepalladium dichloride Dichlorobis(phenyl cyanide)palladium Palladium dichloride bis(benzonitrile) Bis(benzonitrile)palladiuM(II)chloridel Bis(benzonitrile)palladiuM(II) chloride 95% Bis (benzonitrile) palladiuM bis(benzonitrile)dichloro-Palladium Bis(benzonitrile)-palladium(II) chloride (27.7% Pd) for synthesis PALLADIUM(II) CHLORIDE BIS(BENZONITRILE) COMPLEX TRANS-DICHLOROBIS-(BENZONITRILO)-PALLADIUM TRANS-BIS(BENZONITRILE)DICHLOROPALLADATE (II) TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II) BIS(BENZONITRILE)DICHLOROPALLADIUM(II) Bis(benzonitrile)palladium chloride Bis(benzonitrile)palladium(II) chloride, 99+% trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7% Trans-Bis(benzonitrile)dichloropalladium(II) Can be used to form catalysts in situ by separate addition of ligand Dichlorobis(benzonitrile)palladium(II),99% Palladium, bis(benzonitrile)dichloro- Palladium(II)chloro-bis(benzonitrile) trans-Bis(benzonitrile)dichloropalladium(II), Pd Dichlorobis(benzonitrile)palladium (II) ,98% trans-Bis(benzonitrile)dichloropalladiuM(II), Pd 27.1% Bis(benzonitrile)palladiuM(II) chloride, 99+% 1GR Dichlorodiamminepalladium(II) PdCl2(C6H5CN)2 is(benzonitrile)palladium chloride Bis(benzonitrile)palladium(II) chloride 95+% Dichlorobis(benzonitrile)palladium(II) ,(C6H5CN)2PdCl2 Benzonitrile - dichloropalladium (2:1) Bis(benzonitrile)palladium(II) Dichloride > Bis(benzonitrile)dichloropalladium(Ⅱ) Bis(benzonitriL Bis(benzonitrile)palladium chloride ISO 9001：2015 REACH Bis(benzonitrile)palladium(II)chloride 14220-64-5 Bis(benzonitrile)palladium(II) Dichloride extrapure, 27.4% Pd BIS (BENZONITRILE) DICHLORO PALLADIUM (II) For synthesis Pd(PhCN)2Cl2 Dichlorobis(benzonitrile)palladium BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE DICHLOROBIS(BENZONITRILE)PALLADIUM(II) Bis(benzonitrile)palladiuM(II) Bis(benzonitrile)palladium dichloride Bis(benzonitrile 14220-64-5 PdCl2C6H5CN2 C6H5CN2PdCl2 C14H10N2PdCl2 C14H10Cl2N2Pd 2C7H5NCl2Pd Classes of Metal Compounds Transition Metal Compounds