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(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester

(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester Structure
(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester structure
CAS No.
2447-72-5
Chemical Name:
(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester
Synonyms
Picraphylline;(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester;Pyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid, 4,4a,5,6,7,8,13,14,15,15a-decahydro-4,6-dimethyl-14-oxo-, methyl ester, (4S,4aS,15aS)- (9CI)
CBNumber:
CB52292529
Molecular Formula:
C22H26N2O4
Molecular Weight:
382.45
MDL Number:
MOL File:
2447-72-5.mol
Request For Quotation

(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester Properties

Melting point 255°C
Boiling point 559.9±50.0 °C(Predicted)
Density 1.198±0.06 g/cm3(Predicted)
pka 15.10±0.60(Predicted)

(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester Chemical Properties,Uses,Production

Description

Isolated from the flowers of Picralima nitida Stapf., this base has [α]20D - 37° (CHCI3) and gives an ultraviolet spectrum in EtOH with absorption maxima at 238 and 313 mil. The structure has been elucidated by spectroscopic methods.

References

Ledouble et al., Ann. Pharm., 22,463 (I 964)
Levyetal., Bull. Soc. Chim. Fr., 1917 (1964)

(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(4S,4aS,15aS)-4,4a,5,6,7,8,13,14,15,15a-Decahydro-4,6-dimethyl-14-oxopyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid methyl ester Picraphylline Pyrano[4',3':8,9]azecino[5,4-b]indole-1-carboxylic acid, 4,4a,5,6,7,8,13,14,15,15a-decahydro-4,6-dimethyl-14-oxo-, methyl ester, (4S,4aS,15aS)- (9CI) 2447-72-5