ChemicalBook >> CAS DataBase List >>Trimethylsulfoxonium iodide
Trimethylsulfoxonium iodide
- CAS No.
- 1774-47-6
- Chemical Name:
- Trimethylsulfoxonium iodide
- Synonyms
- TMSOI;Trimethylsulfoxonium;TRIMETHYLSULPHOXONIUM IODIDE;Trimethyl sulfoxide iodide;trimethyloxosulphonium iodide;TriMethyloxosulfoniuM Iodide;NSC 71213;foxonium iodide;RARECHEM AQ A1 0066;Trimethyl sulfoxide
- CBNumber:
- CB5304873
- Molecular Formula:
- C3H9IOS
- Molecular Weight:
- 220.07
- MDL Number:
- MFCD00011899
- MOL File:
- 1774-47-6.mol
- MSDS File:
- SDS
Last updated:2024-05-21 21:51:03
Melting point | 208-212 °C (dec.) (lit.) |
---|---|
Density | 1.7074 (estimate) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | H2O: 50 mg/mL, clear |
form | Crystalline Powder |
color | White to light yellow |
PH | pH(50g/l, 25℃) : 4.8~6.0 |
Water Solubility | 15 g/L (20 ºC) |
Sensitive | Light Sensitive |
BRN | 3595854 |
InChI | InChI=1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1 |
InChIKey | BPLKQGGAXWRFOE-UHFFFAOYSA-M |
SMILES | [S+](=O)(C)(C)C.[I-] |
CAS DataBase Reference | 1774-47-6(CAS DataBase Reference) |
EPA Substance Registry System | Sulfoxonium, trimethyl-, iodide (1774-47-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 36/37/38-22 | |||||||||
Safety Statements | 37/39-26-36-24/25 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | WS3585000 | |||||||||
F | 8 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29309070 | |||||||||
NFPA 704 |
|
Trimethylsulfoxonium iodide price More Price(36)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | T80500 | Trimethylsulfoxonium iodide 98% | 1774-47-6 | 100g | $49.14 | 2024-03-01 | Buy |
Sigma-Aldrich | T80500 | Trimethylsulfoxonium iodide 98% | 1774-47-6 | 25g | $60.7 | 2024-03-01 | Buy |
TCI Chemical | T1065 | Trimethylsulfoxonium Iodide >98.0%(T) | 1774-47-6 | 25g | $22 | 2024-03-01 | Buy |
TCI Chemical | T1065 | Trimethylsulfoxonium Iodide >98.0%(T) | 1774-47-6 | 100g | $60 | 2024-03-01 | Buy |
Alfa Aesar | A14589 | Trimethylsulfoxonium iodide 98+% | 1774-47-6 | 25g | $20.65 | 2024-03-01 | Buy |
Trimethylsulfoxonium iodide Chemical Properties,Uses,Production
Chemical Properties
WHITE TO LIGHT YELLOW CRYSTALLINE POWDER
Uses
Trimethylsulfoxonium iodide is a sulfoxonium salt. It is used to generate dimethyloxosulfonium methylide by reaction with sodium hydride. The latter compound is used as a methylene-transfer reagent, and is used to prepare epoxides.
Uses
Trimethylsulfoxonium Iodide is used to synthesize methylene-transfer reagents that are used in the preparation of epoxides.
Uses
Treatment with strong base yields the ylide which adds to the carbonyl group of ketones1 and aldehydes2,3 to give epoxides. Also adds preferentially to the double bond of α,β-unsaturated esters to give cyclopropyl esters.4,5
Trimethylsulfoxonium iodide Preparation Products And Raw materials
Raw materials
Preparation Products
Styrene oxide
1-BOC-4-HYDROXY-4-(HYDROXYMETHYL)-PIPERIDINE
2-(1-Adamantyl)oxirane
10-methoxy-1,6-dimethylergoline-8beta-methanol
Methanone, [2-(4-methoxyphenyl)cyclopropyl]phenyl-
1of3
Global( 616)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Joyochem Co.,Ltd | +86-0531-82687558 +8613290333633 | sales@joyochem.com | China | 41 | 58 |
Jinan Dexinjia Bio&Tech Co., Ltd | +86-0531-82375893 +86-15553111391 | sales@jndxj.com | China | 1201 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12471 | 58 |
Hebei Jingbo New Material Technology Co., Ltd | +8619931165850 | hbjbtech@163.com | China | 1000 | 58 |
Hebei Saisier Technology Co., LTD | +86-18400010335 +86-18034520335 | admin@hbsaisier.cn | China | 938 | 58 |
Hebei Longbang Technology Co., LTD | +86-18032476855 +86-18032476855 | admin@hblongbang.com | China | 565 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | forrest.lee@dakenchem.com | China | 15956 | 58 |
Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 | sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
View Lastest Price from Trimethylsulfoxonium iodide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-05-21 | Trimethylsulfoxonium iodide
1774-47-6
|
US $6.00 / KG | 1KG | 99% | 20TONS | Hebei Longbang Technology Co., Ltd | ||
2024-04-28 | Trimethylsulfoxonium iodide
1774-47-6
|
US $6.00 / KG | 1KG | More than 99% | 2000KG/Month | Hebei Saisier Technology Co., LTD | ||
2023-12-25 | Trimethylsulfoxonium iodide
1774-47-6
|
US $9.00 / kg | 1kg | 99% | 200000 | Hebei Jingbo New Material Technology Co., Ltd |
- Trimethylsulfoxonium iodide
1774-47-6
- US $6.00 / KG
- 99%
- Hebei Longbang Technology Co., Ltd
- Trimethylsulfoxonium iodide
1774-47-6
- US $6.00 / KG
- More than 99%
- Hebei Saisier Technology Co., LTD
- Trimethylsulfoxonium iodide
1774-47-6
- US $9.00 / kg
- 99%
- Hebei Jingbo New Material Technology Co., Ltd
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rimethylsulfoxonium iodide
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TRIMETHYLSULFOXONIUMIODIDE FOR SYNTHESIS
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TriMethylsulfoxoniuM iodide SynonyMs TriMethylsulphoxoniuM iodide
SulfoxoniuM,triMethyl-, iodide (1:1)
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Three Methyl iodide sulfoxide
S,S,S-Trimethylsulfoxonium iodide
Trimethylsulfonium iodide, oxide
trimethylsulfoxoniuim iodide
Trimethysulfoxonium Iodide
Trimethylsulfoxonium iodate
TrimethyloxosulfoniumIodideTmsoi
TrimethylSulfoxoniumIodide(Tmsoi)
Trimethylsulfoxonium iodide, 98+%
Trimethylsulphoxonium iodide, 98+%
RARECHEM AQ A1 0066
TRIMETHYLSULFOXONIUM IODIDE
Trimethylsulphoxonium iodide 98%
Trimethyl sulfoxide
Fluconazole Impurity 7 (Trimethylsulfoxonium Iodide)
Fluconazole Impurity 7
TRI-METHYL SULPHOXONIUM IODIDE (TMSI)
Trimethylsulfoxonium iodide, 98%, for synthesis
foxonium iodide
TRIMETHYLSULFOXONIUM IODIDE (TMSOI), CAS NO. 1774-47-6
Trimethyl sulphoxonium iodide for synthesis 100GM
Trimethyl sulphoxonium iodide for synthesis 500GM
Trimethylsulfoxonium Iodide (TMSI) extrapure, 99%
TRIMETHYLSULFOXONIUM IODIDE Extra Pure
Trimethyl sulfoxide iodide
TriMethyloxosulfoniuM Iodide
trimethyloxosulphonium iodide
Trimethylsulfoxonium
TRIMETHYLSULPHOXONIUM IODIDE
TMSOI
Fluconazole Impurity 38
Trimethyloxosulfoniumiodid
Trimethylsulfoxonium
Iodide (TMSI)
1774-47-6
C3H9OSI
CH33SOI
CH33SIO
C3H9IOS
Iodonium Sulfonium & Oxonium Compounds
Sulfur Compounds (for Synthesis)
Sulfonium Compounds