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4-Nitrobenzyl bromide

4-Nitrobenzyl bromide structure

CAS No.: 100-11-8

Chemical Name:: 4-Nitrobenzyl bromide

Synonyms: 1-(BROMOMETHYL)-4-NITROBENZENE;PARA NITRO BENZYL BROMIDE;P-NITROBENZYL BROMIDE;4NBB;Nitrobenzyl bromide;4-Nitrobenzyl;AKOS BBS-00004545;Nitrobenzyl broMid;p-Nitobenzylbromide;Nitro broMine benzyl

CBNumber:: CB5485712

Molecular Formula:: C7H6BrNO2

Molecular Weight:: 216.03

MDL Number:: MFCD00007373

MOL File:: 100-11-8.mol

MSDS File:: SDS

Last updated:2023-05-15 10:43:11

4-Nitrobenzyl bromide Properties

Melting point	98 °C
Boiling point	265.51°C (rough estimate)
Density	1.6841 (rough estimate)
refractive index	1.6120 (estimate)
storage temp.	Store at RT.
solubility	soluble in Chloroform, Ethyl Acetate
form	Crystalline Powder
color	Light yellow to beige
Water Solubility	It hydrolyzes in water. Soluble in alcohol and ether.
BRN	742796
Stability	Stable. Incomaptible with bases, amines, oxidizing agents, alcohols. May be moisture sensitive. Corrodes steel.
CAS DataBase Reference	100-11-8(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	QCHRSPCHUE
NIST Chemistry Reference	Benzene, 1-(bromomethyl)-4-nitro-(100-11-8)
EPA Substance Registry System	Benzene, 1-(bromomethyl)-4-nitro- (100-11-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H314-H335

Precautionary statements

P260-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338

Hazard Codes

C,Xi

Risk Statements

Safety Statements

26-36/37/39-45

RIDADR

UN 3261 8/PG 2

WGK Germany

RTECS

XS7967000

10-19-21

Hazard Note

Irritant/Corrosive

TSCA

Yes

HazardClass

PackingGroup

HS Code

29049085

NFPA 704

	1
3		0

4-Nitrobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

4-Nitrobenzyl bromide is used in the synthesis of di and tri-substituted azoles. It is also used in the preparation of N6-Benzyladenosine-5?-uronamides as selective A3 adenosine agonists.

Definition

ChEBI: A C-nitro compound that consists of nitrobenzene bearing a bromomethyl substituent at the para-position.

Purification Methods

Recrystallise the bromide four times from absolute EtOH, then twice from cyclohexane/hexane/*benzene (1:1:1), followed by sublimation at 0.1mm and final recrystallisation from the same solvent mixture. [Lichtin & Rao J Am Chem Soc 83 2417 1961.] It has also been crystallised from pet ether (b 80-100o, 10mL/g, charcoal). It slowly decomposes even when stored in a desiccator in the dark. IRRITANT. [Beilstein 5 IV 861.]

4-Nitrobenzyl bromide Preparation Products And Raw materials

Raw materials

4-Nitrotoluene

Preparation Products

DIETHYL(4-NITROBENZYL)PHOSPHONATE FLUCYCLOXURON 4-(Morpholinomethyl)aniline 2-Nitro-3-pyridinamine N,N-DIBENZYL GLYCINE METHYL ESTER

1-(4-Nitrophenyl)methyl-1,2,4-triazole (4-Nitrophenyl)methanesulfonyl chloride 4-Aminobenzylamine 4-AMINO-N,N-DIMETHYLBENZYLAMINE

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4-Nitrobenzyl bromide Spectrum

4-Nitrobenzyl bromide(100-11-8)MS 4-Nitrobenzyl bromide(100-11-8)¹HNMR 4-Nitrobenzyl bromide(100-11-8)¹³CNMR 4-Nitrobenzyl bromide(100-11-8)IR1 4-Nitrobenzyl bromide(100-11-8)IR2 4-Nitrobenzyl bromide(100-11-8)Raman

100-11-8(4-Nitrobenzyl bromide)Related Search:

4-Cyanobenzyl bromide 4-Nitrobenzenesulfonyl chloride 4-Nitrobenzyl chloroformate 4-Nitrophenol 4-Nitrotoluene

Sodium bromate Rocuronium bromide (4-Nitrophenyl)methyl 3-oxobutanoate BRETYLIUM TOSYLATE Dimidium bromide

Benzyl bromide Vecuronium bromide 4-Nitrobenzoic acid 4-Nitrobenzonitrile 4-Nitrobenzyl alcohol

Allyl bromide Ethidium bromide 4-Nitrobenzyl chloride

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4-Nitrobenzyl bromide, 97+% 4-nitrobenzyl bormide 4-Nitrobenzyl Benzene, 1-(bromomethyl)-4-nitro- à-bromo-4-nitrotoluene 4-Nitrobenzyl bromide 98% BROMOMETHYL-4-NITROBENZENE p-NITROBENZYL BROMIDE pure Pare Nitro Benzyl Bromide alpha-bromo-p-nitro-toluen -Bromo-4-nitro-toluene p-(Bromomethyl)nitrobenzene p-Nitobenzylbromide Toluene, alpha-bromo-4-nitro- Toluene, alpha-bromo-p-nitro- p-nitoro benzyl bromide 4-Nitrobenzyl bromide,99% α-Bromo-p-nitrotoluene ω-Bromo-p-nitrotoluene 4-Nitrobenzyl bromide,α-Bromo-4-nitrotoluene alpha-Bromo-4-nitrotoluene, 1-(Bromomethyl)-4-nitrobenzene, 4-(Bromomethyl)nitrobenzene Nitro broMine benzyl 4-Nitrobenzyl broMide, 99% 100GR 4-Nitrobenzyl broMide, 99% 25GR Nitrobenzyl broMid The nitro benzyl broMide 4-Nitrobenzyl bromide≥ 99.5% (assay) 1-(bromomethyl)-4-nitro-benzen 4-(bromomethyl)nitrobenzene alpha-Bromoparanitrotoluene NITROBENZYL-4 BROMIDE ALPHA-BROMO-4-NITROTOLUENE ALPHA-BROMO-P-NITROTOLUENE AKOS BBS-00004545 a-Brom-4-nitrotoluol A-BROMO-P-NITROTOLUENE 4-NITROBENZYL BROMIDE p-Nitrobenzyl bromide(4-Nitrobenzyl bromide) a-Bromo-4-nitrotoluene Para-Nitro Benzyl Bromide (PNBBr) CAS No. : 100-11-8 4-NitrobenzylBromide> 4-Nitrobenzyl Bromide,>98% Para‐Nitro?Benzyl?Bromide?(PNBBr) p-Nitrobenzyl Bromide (PNBBR) pure, 98% P-NITROBENZYL BROMICE 99% Nitrobenzyl bromide P-NITROBENZYL BROMIDE PARA NITRO BENZYL BROMIDE 1-(BROMOMETHYL)-4-NITROBENZENE 4NBB Nifedipine Impurity 37 4-Nitrobenzyl Bromide Cefaclor intermediate 100-11-8 110-11-8 11011-8 O2NC6H4CH2Br BrCH2C6H4NO3 Br1C7H6N1O2