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Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide structure

CAS No.: 54678-23-8

Chemical Name:: Copper(I) bromide-dimethyl sulfide

Synonyms: COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%

CBNumber:: CB6332325

Molecular Formula:: C2H6BrCuS

Molecular Weight:: 205.58

MDL Number:: MFCD00043295

MOL File:: 54678-23-8.mol

MSDS File:: SDS

Last updated:2023-10-16 16:12:12

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Copper(I) bromide-dimethyl sulfide Properties

Melting point	132 °C (dec.)(lit.)
form	Crystalline Powder and/or Chunks
color	Pale brown or pale green
Water Solubility	Soluble in water. Reacts with water and decomposes.
Sensitive	Moisture Sensitive/Air Sensitive
BRN	4386581
Exposure limits	ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey	PMHQVHHXPFUNSP-UHFFFAOYSA-M
CAS DataBase Reference	54678-23-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P280g-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-24/25

RIDADR

1759

WGK Germany

10-13-21

HazardClass

PackingGroup

III

HS Code

29309090

NFPA 704

	0
0		0

Copper(I) bromide-dimethyl sulfide price More Price(28)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	230502	Copper(I) bromide dimethyl sulfide complex 99%	54678-23-8	10g	$118	2024-03-01	Buy
Sigma-Aldrich	230502	Copper(I) bromide dimethyl sulfide complex 99%	54678-23-8	50g	$320	2024-03-01	Buy
Alfa Aesar	019368	Copper(I) bromide-dimethyl sulfide complex	54678-23-8	2g	$22.65	2024-03-01	Buy
Alfa Aesar	019368	Copper(I) bromide-dimethyl sulfide complex	54678-23-8	10g	$84.6	2024-03-01	Buy
Strem Chemicals	29-0225	Copper(I) bromide, dimethyl sulfide complex, 99%	54678-23-8	25g	$225	2021-12-16	Buy

Product number	Packaging	Price	Buy
230502	10g	$118	Buy
230502	50g	$320	Buy
019368	2g	$22.65	Buy
019368	10g	$84.6	Buy
29-0225	25g	$225	Buy

Copper(I) bromide-dimethyl sulfide Chemical Properties,Uses,Production

Chemical Properties

off-white to beige, grey or green crystalline

Uses

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Uses

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

Uses

Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 3-furancarboxylate 3-FURANMETHANOL

Copper(I) bromide-dimethyl sulfide Suppliers

Global( 169)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12471	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21689	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Shandong chuangyingchemical Co., Ltd.	18853181302	sale@chuangyingchem.com	CHINA	5909	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12711	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Hubei xin bonus chemical co. LTD	58
Shandong chuangyingchemical Co., Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-10-16	Copper(I) bromide-dimethyl sulfide 54678-23-8	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-06	Copper(I) bromide-dimethyl sulfide 54678-23-8	US $0.00-0.00 / KG	1KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.
2019-08-06	Copper(I) bromide-dimethyl sulfide 54678-23-8	US $1.00 / KG	1KG	98%	10KG	Career Henan Chemical Co

Copper(I) bromide-dimethyl sulfide
54678-23-8
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Copper(I) bromide-dimethyl sulfide
54678-23-8
US $0.00-0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

Copper(I) bromide-dimethyl sulfide
54678-23-8
US $1.00 / KG
98%
Career Henan Chemical Co

Copper(I) bromide-dimethyl sulfide Spectrum

Copper(I) bromide-dimethyl sulfide(54678-23-8)FT-IR Copper(I) bromide-dimethyl sulfide(54678-23-8)IR

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bromo[thiobis[methane]]copper CUPROUS BROMIDE METHYLSULFIDE COMPLEX BROMO(DIMETHYLSULFIDE)COPPER(I) Copper(I) bromide methylsulfide complex Copper, bromothiobismethane- COPPER BROMIDE-DIMETHYL SULFIDE Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex Copper(i)bromide-dimethyl sulfide complex,99% Copper (I) bromide dimethylsulphide complex Copper(I) bromide dimethyl sulfide complex,Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex Copper (I) bromide dimethylsulphide complex 99% Copper(I) broMide-diMethyl sulfide coMplex, 99% 10GR Copper(Ⅰ) bromide-dimethyl sulfide complex Copper(I) broMide diMethyl sulfide coMplex 99% COPPERBROMIDE-DIMETHYL SULFIDE COMPLEX Cuprous bromide dimethyl sulfide complex COPPER(1) BROMIDE DMS COMPLEX 95% Copper(I) bromide-dimethyl sulfide ISO 9001：2015 REACH C**Copper(I) bromide-dimethyl sulfide Copper(I) bromide methyL COPPER(I) BROMIDE DIMETHYL SULFIDE COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX Bromocopper COPPER(1)BROMIDE DMS COMPLEX 54678-23-8 CuBrSCH32 C2H6BrCuS CuBrCH3SCH3 CH32SCuBr C2H6SBrCu BrC2CuH6S Catalysis and Inorganic Chemistry