ChemicalBook >> CAS DataBase List >>dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin

dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin

CAS No.
57345-19-4
Chemical Name:
dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
Synonyms
amber oxepin;AMBER KETAL IPM;Einecs 260-686-4;KETAMBER 10 P. IN APV;dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin;5H-3,5a-Epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl-;5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane;5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane;1,2,3,6,7,7a,8,9,10,11,11a,11b-Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
CBNumber:
CB6942579
Molecular Formula:
C18H30O2
Molecular Weight:
278.43
MDL Number:
MOL File:
57345-19-4.mol
Last updated:2023-05-25 18:01:16

dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin Properties

Boiling point 300.9±10.0 °C(Predicted)
Density 1.05±0.1 g/cm3(Predicted)
vapor pressure 0.001Pa at 20℃
form Solid:bulk
Odor at 10.00 % in dipropylene glycol. dry amber powdery woody musk
Odor Type amber
LogP 5.9 at 30℃ and pH7
EPA Substance Registry System 5H-3,5a-Epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl- (57345-19-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H413-H315
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362

dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin Chemical Properties,Uses,Production

Chemical Properties

Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin is a colorless to pale yellow liquid. It possesses a powerful amber note with good stability in nonaggressive media.

Preparation

The synthesis starts from the natural raw material manool, which is obtained by extraction from a tree growing in New Zealand, the so-called pink pine, Halocarpus biformis (Hooker) C.J. Quinn. Epoxidation of manool, subsequent oxidative degradation of the allylalcohol side chain to yield a ketone, and intramolecular acetalization afford the ketal.

Trade name

Ambermore Ketal (Aromor), Amberketal (Givaudan), Z11 (Firmenich).

dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin Preparation Products And Raw materials

Raw materials

Preparation Products

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dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin KETAMBER 10 P. IN APV 5H-3,5a-Epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl- AMBER KETAL IPM 1,2,3,6,7,7a,8,9,10,11,11a,11b-Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin Einecs 260-686-4 5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane 5,5,9,13-Tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane amber oxepin 57345-19-4 Organics