(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide
- CAS No.
- 34029-94-2
- Chemical Name:
- (7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide
- Synonyms
- Laurepukin;Laurepukine;(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide
- CBNumber:
- CB82368335
- Molecular Formula:
- C18H17NO4
- Molecular Weight:
- 311.33188
- MDL Number:
- MOL File:
- 34029-94-2.mol
(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide Properties
Melting point | 230-231° |
---|---|
alpha | D -222° (c = 0.022 in chloroform) |
FDA UNII | MCN6QK3FK3 |
(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide price
(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide Chemical Properties,Uses,Production
Description
The alkaloid originally isolated under this name by Aston proved to be a mixture of laureline and pukateine and the name was then given to a third alkaloid occurring in the bark of Laurelia Novae-Zelandae. The base crystallizes in colOUrless needles or hexagonal tablets and is laevorotatory with [α]D - 222° (CHCl 3 ). The sulphate hexahydrate, m.p. 99-l00°C is almost completely insoluble in H20; the methiodide has m.p. 249-250°C and the O,G-dimethyl ether forms colourless prisms, m.p. l34°C, b.p. 200-2l0°C/l0 mm; [α]D - 314° (CHC13). The probable structure, given above, has been deduced by comparison with other, similar alkaloids although the alternative structure 3 :4-dihydroxy- 6:7-methylenedioxyaporphine, is not completely excluded.
References
Aston.,J. Chem. Soc., 97, 1381 (1910)
Barger, Girardet., Helv. Chim. Acta., 14, 481 (1931)
Girardet., ibid, 14, 504 (1931)
Govindachari et al., Chem. Ber., 91, 36 (1958)
(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide Preparation Products And Raw materials
Raw materials
Preparation Products
(7R)-6,7,7aβ,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-12-ol 7-oxide Suppliers
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