Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 物理性質
- 融点 :
- 153 °C (dec.)(lit.)
- 貯蔵温度 :
- 2-8°C
- 溶解性:
- Chloroform (Slightly), Dichloromethane (Sparingly)
- 外見 :
- solid
- 色:
- Purple
- Merck :
- 13,4565
- InChI:
- InChI=1S/2C18H33P.C7H5.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;2-6H;2*1H;/q;;-2;;;+2
- InChIKey:
- PNPBGYBHLCEVMK-UHFFFAOYSA-L
- SMILES:
- [Ru+4]([Cl-])([Cl-])(=[C-2]C1C=CC=CC=1)(P(C1CCCCC1)(C1CCCCC1)C1CCCCC1)P(C1CCCCC1)(C1CCCCC1)C1CCCCC1
- CAS データベース:
- 172222-30-9
安全性情報
- リスクと安全性に関する声明
- 危険有害性情報のコード(GHS)
絵表示(GHS) |
|
注意喚起語 |
警告 |
危険有害性情報 |
コード |
危険有害性情報 |
危険有害性クラス |
区分 |
注意喚起語 |
シンボル |
P コード |
H228 |
可燃性固体 |
可燃性固体 |
1 2 |
危険 警告 |
|
P210, P240,P241, P280, P370+P378 |
|
注意書き |
P210 |
熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。 |
|
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 価格
もっと(3)
メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
Sigma-Aldrich Japan
|
579726 |
97%
Grubbs Catalyst? 1st Generation 97% |
172222-30-9 |
1g |
¥20800 |
2024-03-01 |
購入 |
Sigma-Aldrich Japan
|
579726 |
97%
Grubbs Catalyst? 1st Generation 97% |
172222-30-9 |
5g |
¥83300 |
2024-03-01 |
購入 |
Sigma-Aldrich Japan
|
579726 |
Umicore, 97%
Grubbs触媒® M102 Umicore, 97% |
172222-30-9 |
50G |
¥667000 |
2024-03-01 |
購入 |
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 化学特性,用途語,生産方法
化学的特性
bright purple powder
使用
suzuki reaction
純化方法
Wash it repeatedly with Me2CO and MeOH and dry it in a vacuum. Alternatively dissolve it in CH2Cl2, concentrate it to half its volume, filter, add MeOH to precipitate it as purple microcrystals. Filter these off, wash several times with Me2CO and MeOH and dry them in a vacuum for several hours. [Scwab et al. J Am Chem Soc 118 100 1996, Miller et al. J Am Chem Soc 118 9606 1996, Furstner & Langermann J Am Chem Soc 119 9130 1997.] § A polymer supported version is available [Schwab et al. Angew Chem (Intl Edn) 34 2039 1995.].
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 上流と下流の製品情報
原材料
準備製品
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 生産企業
Global( 290)Suppliers
172222-30-9()キーワード:
- 172222-30-9
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- Phenylmethylenebis(tricyclohexlPhosPhine)ruthenium chloride
- GRUBB'S CATALYST 97%
- Bis-(tricyclohexylphosphine)-benzylideneruthenium
- Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(IV)
- Bis(tricyclohexylphosphine)benzylidine ruthenium(lV) dichloride
- Grubbs (1st generation)
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniuM,Grubbs Catalyst 1st Generation
- Benzylidene-bis(tricyclohexylp
- Benzylidene-bis(tricyclohexylphosphine)dichlororut
- RutheniuM,dichloro(phenylMethylene)bis(tricyclohexylphosphine)-, (SP-5-31)-
- Grubbs Catalyst, 1st Generation 97%
- Benzylidenebis(tricyclohexylphosphoranyl)ruthenium(VI) chloride
- NAD+, Free Acid
- Grubbs catalyst 1st generation
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- bis(tricyclohexylphosphine)benzylidine ruthenium dichloride
- (Benzylidene)bis(tricyclohexylphosphine)ruthenium(4) Dichloride
- Grubbs Catalyst, 1st generation,Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine) benzylidine ruthenium(IV) chloride
- Bis(tricyclohexylphosphine)benzylidine ruthenium (IV) dichloride GRUBBS'S CATALYST
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine) benzylidine ruthenium(IV) chloride
- Grubb's catalyst,97%
- tricyclohexyl[dichloro(phenylMethylidene)(tricyclohexyl-$l^{5}-phosphanyl)ruthenio]-$l^{5}-phosphane
- Dichloro[(benzylidene)bis(tricyclohexylphosphine)]- rutheniuM(II)
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniuM, Grubbs Catalyst 1st Generation Grubbs
- BENZYLIDENE-BIS(TRIPHENYLPHOSPHINE)RUTHENIUM DICHLORIDE
- BIS(TRICYCLOHEXYLPHOSPHINE)BENZYLIDENERUTHENIUM(IV) DICHLORIDE
- GRUBB'S CATALYST
- GRUBBS CATALYST, 1ST GENERATION
- RUTHENIUM,DICHLORO(PHENYLMETHYLENE)BIS (TRICYCLOHEXYLPHOSPHINE)
- ruthenium phosphine