シマジン 化学特性,用途語,生産方法
外観
白色, 結晶～粉末
溶解性
1,4-ジオキサンに溶け、アセトンに溶けにくく、エタノールに極めて溶けにくく、水にほとんど溶けない。
解説
シマジン,白色の結晶．融点225～227 ℃．一般有機溶媒に難溶．果樹園，非農耕地に使用される非ホルモン系移行型の光合成阻害型除草剤として用いられる．トウモロコシには選択性を有し，薬害が認められない．
森北出版「化学辞典（第2版）
用途
農薬(除草剤) (NITE CHRIP)
製造
シマジン,代表的なトリアジン系除草剤の一つ．塩化シアヌルとエチルアミンとを反応させて合成する．
毒性
LD50 5000 mg/kg(ラット，経口)．
農薬用途
除草剤
化学的特性
Simazine is a combustible, white crystalline solid. Practically odorless.Its solubility in methanol is 400mg/L, its solubility in water is 5mg/L, its solubility in petroleum ether is 2mg/L and it is slightly soluble in chloroform. It has the advantages of stable chemical property, but it is easily hydrolyzed under the strong acid or alkali conditions and at higher temperatures to produce inactive hydroxyl derivatives. No corrosion. Original medicine m.p.224℃.
使用
Simazine is a preemergence herbicide used to control
broadleaf and grassy weeds. It is also used as a soil sterilant.
Principal crops involved include maize, citrus, and deciduous
fruit. Simazine is also used in aquatic weed control.
調製方法
Simazine is prepared by reacting two equivalents of ethylamine
in the presence of an acid acceptor. It is stable in neutral
and slightly basic or acidic media, but is hydrolyzed by
stronger acids and bases especially at higher temperatures.
Primary exposures occur during application, not during
production, and include both inhalation and dermal components.
定義
ChEBI: A diamino-1,3,5-triazine that is N,N'-diethyl-1,3,5-triazine-2,4-diamine substituted by a chloro group at position 6.
一般的な説明
White to off-white crystalline powder.
空気と水の反応
Insoluble in water.
反応プロフィール
Simazine is hydrolyzed by strong acids and alkalis .
健康ハザード
Inconsistent data in the literature; oral LD50values in rats reported as 970 and 5000 mg/L,showing a wide difference; toxicity is of loworder.
火災危険
Literature sources indicate that Simazine is nonflammable.
农业用途
Pre-emergence herbicide, Algaecide: and ornamental crops, turf grass, orchards, and vineyards. At higher rates, it is used for non-selective weed control in industrial areas. Before 1992, simazine was used to control submerged weeds and algae in large aquariums, farm ponds, fish hatcheries, swimming pools, ornamental ponds, and cooling towers. Simazine is available in wettable powder, waterdispersible granule, liquid, and granular formulations. It may be soil-applied. Not approved for use in EU countries. A U.S. EPA restricted Use Pesticide (RUP) for all land uses because of its potential to contaminate ground water
製品名
AKTINIT S®; ALCO® Simizine; AQUAZINE®; ATLAS SIMAZINE®; BATAZINA®; BITEMOL®; CALIBER®; CDT®; CEKUSAN®; CEKUZINA-S®; FRAMED®; G 27692®; GEIGY 27692®; GESARAN®; GESATOP®; GESATOP-50®; H 1803®; HARLEQUIN®; HERBAZIN® 500 BR; HERBAZIN® 50; HERBEX®; HERBOXY®; HUNGAZIN DT®; OXON ITALIA SIM-TROL®; PREMAZINE®; PRIMATEL S®; PRIMATOL S®; PRINCEP®; PRINCEP® 80W; SIMADEX®; SIMANEX®; SIMAZINE® 80W; SIMAZAT®; SIM-TROL®; TAFAZINE®; TAFAZINE® 50-W; TANZINE®; TAPHAZINE®; TOTAZINE®; TRIAZINE A 384®; W 6658®; WEEDEX®; ZEAPUR®
職業ばく露
A potential danger to those involved in the manufacture, formulation, and application of this preemergence herbicide. Pesticide not in use; TRI and/or IUR indicates importers or manufacturers are unlikely. Banned for use in the EU.
発がん性
No tumorigenic response was
seen in mice treated orally at doses ranging from 75 to
215mg/kg. In a 2-year feeding study in rats, 100 ppm
produced mammary tumors. Sarcomas at the injection
sitewere produced in another study ofboth rats and mice.
Simazinewas fedtoratsatdoselevelsequivalent to 0,0.5,5,and
50mg/kg for 2 years.Bodyweight and hematological changes
were seen primarily at the highest dose. After 24 months at
50mg/kg, an increase in ovarian atrophy and Sertoli cell
hyperplasia were seen. Increases in mammary gland tumors
were seen in females at 50mg/kg.
輸送方法
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN2763 Triazine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
不和合性
Powder may form explosive mixture with air. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
廃棄物の処理
Strong acid or alkaline hydrolysis leads to complete degradation of simazine. However,large quantities of simazine should be incinerated in a unit operating @ 850℃ equipped with off-gas scrubbing equipment. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
シマジン 上流と下流の製品情報
原材料
準備製品
2,4-ビス(エチルアミノ)-6-メチルチオ-1,3,5-トリアジン
Acetamide, N-[4-(ethylamino)-1,6-dihydro-6-oxo-1,3,5-triazin-2-yl]-
2-クロロ-4,6-ジアミノ-1,3,5-トリアジン