O12'-デメチルセコオバベリン

O12'-デメチルセコオバベリン 価格

メーカー	製品番号	製品説明	CAS番号	包装	価格	更新時間	購入

O12'-デメチルセコオバベリン 化学特性,用途語,生産方法

説明

This alkaloid is the first isoquinolone-benzylisoquinoline alkaloid to be discovered and occurs in the basic extract from Berberis baluchistanica. It forms colourless crystals when purified by recrystallization from cyc1ohexane-C6H6 and gives an ultraviolet spectrum in EtOH with absorption maxima at 282, 294 and 305 nm, showing a bathochromic shift in acid and alkali due to the presence of a phenolic hydroxyl group in the molecule. Diazomethane in Et20 furnishes the O-methyl ether, m.p. lOS-8°C having an ultraviolet spectrum in EtOH with absorption maxima at 226, 262 and 270 nm and shoulders at 283, 292 and 305 nm. Baluchistanamine itself may be obtained by oxidation of oxyacanthine with dilute potassium permanganate in Me2CO and the methyl ether is also formed by the same method from obaberine. Since both of these latter bases are also present in B. baluchistanica it suggests that baluchistanamine is produced biogenetically by oxidation of oxyacanthine.

参考文献

Shamma, Foy, Miana, J. Amer. Chem. Soc., 96, 7809 (1974)

O12'-デメチルセコオバベリン 上流と下流の製品情報

原材料

準備製品

O12'-デメチルセコオバベリン 生産企業

名前	電話番号	電子メール	国籍	製品カタログ	優位度

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• 55085-44-4
• 4-Hydroxy-3-[4-[[(1S)-1,2,3,4-tetrahydro-6,7-dimethoxy-2-methyl-8-[(1,2,3,4-tetrahydro-6-methoxy-2-methyl-1-oxoisoquinolin-7-yl)oxy]isoquinolin-1-yl]methyl]phenoxy]benzaldehyde
• Baluchistanamine
• O12'-Demethylsecoobaberine
• Benzaldehyde, 4-hydroxy-3-[4-[[(1S)-1,2,3,4-tetrahydro-6,7-dimethoxy-2-methyl-8-[(1,2,3,4-tetrahydro-6-methoxy-2-methyl-1-oxo-7-isoquinolinyl)oxy]-1-isoquinolinyl]methyl]phenoxy]-
• バルキスタンアミン
• O12'-デメチルセコオバベリン
• 4-ヒドロキシ-3-[4-[[(1S)-1,2,3,4-テトラヒドロ-6,7-ジメトキシ-2-メチル-8-[(1,2,3,4-テトラヒドロ-6-メトキシ-2-メチル-1-オキソイソキノリン-7-イル)オキシ]イソキノリン-1-イル]メチル]フェノキシ]ベンズアルデヒド
• 3-(4-{[(1S)-6,7-ジメトキシ-8-[(6-メトキシ-2-メチル-1-オキソ-1,2,3,4-テトラヒドロイソキノリン-7-イル)オキシ]-2-メチル-1,2,3,4-テトラヒドロイソキノリン-1-イル]メチル}フェノキシ)-4-ヒドロキシベンズアルデヒド
• O12′-デメチルセコオバベリン