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ChemicalBook >> CAS DataBase List >> 1-BROMO-1-PROPENE

1-BROMO-1-PROPENE

1-BROMO-1-PROPENE price.
  • $75 - $587
  • Product name: 1-BROMO-1-PROPENE
  • CAS: 590-14-7
  • MF: C3H5Br
  • MW: 120.98
  • EINECS:209-671-6
  • MDL Number:MFCD00000186
  • Synonyms:1-BROMO-1-PROPENE;1-PROPENYL BROMIDE;PROPENYL BROMIDE;TRANS-1-BROMO-1-PROPENE;1-Brom-1-propen ;1-bromo-1-propen ;1-Bromo-1-propene (cis+trans);1-Bromo-1-propene,cis+trans
Price5 Properties Safety Information Description
5 prices
Selected condition：
Brand
  • AK Scientific
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 5g
  • 10g
  • 25g
  • 100g
  • ManufacturerAK Scientific
  • Product number4765AL
  • Product description1-Bromo-1-propene
  • Packaging5g
  • Price$126
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberB78203
  • Product description1-Bromo-1-propene (cis and trans) 98%
  • Packaging100g
  • Price$587
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberB1038
  • Product description1-Bromo-1-propene (cis- and trans- mixture) >97.0%(GC)
  • Packaging5g
  • Price$79
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberB1038
  • Product description1-Bromo-1-propene (cis- and trans- mixture) >97.0%(GC)
  • Packaging25g
  • Price$237
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberP769100
  • Product description1-PropenylBromide(mixtureofisomers)
  • Packaging10g
  • Price$75
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4765AL 1-Bromo-1-propene 5g $126 2021-12-16 Buy
Sigma-Aldrich B78203 1-Bromo-1-propene (cis and trans) 98% 100g $587 2024-03-01 Buy
TCI Chemical B1038 1-Bromo-1-propene (cis- and trans- mixture) >97.0%(GC) 5g $79 2024-03-01 Buy
TCI Chemical B1038 1-Bromo-1-propene (cis- and trans- mixture) >97.0%(GC) 25g $237 2024-03-01 Buy
TRC P769100 1-PropenylBromide(mixtureofisomers) 10g $75 2021-12-16 Buy

Properties

Melting point :−116 °C(lit.)
Boiling point :64-65 °C(lit.)
Density :1.420 g/mL at 20 °C(lit.)
refractive index :n20/D 1.454
Flash point :5 °F
storage temp. :2-8°C
form :clear liquid
color :Colorless to Light yellow to Light orange
BRN :1719096
CAS DataBase Reference :590-14-7
EPA Substance Registry System :1-Propene, 1-bromo- (590-14-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1-Bromo-1-propene upon n-BuLi treatment generates the propynyllithium anion, in situ, which later undergoes nucleophilic addition reactions. Some of its other applications are:
  • Synthesis of organic reagents such as methyl but-2-ynoate and 1-iodopropyne.
  • Preparation o f intermediates in the total synthesis of (+)-aphanamol I and skyllamycins A-C.
  • Synthesis of allylated pyrazoles, aryl alkynyl sulfides and allenamides.

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