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ChemicalBook >> CAS DataBase List >> DI-TERT-BUTYLCHLOROSILANE

DI-TERT-BUTYLCHLOROSILANE

DI-TERT-BUTYLCHLOROSILANE price.
  • $149.88 - $9975
  • Product name: DI-TERT-BUTYLCHLOROSILANE
  • CAS: 56310-18-0
  • MF: C8H19ClSi
  • MW: 178.77
  • EINECS:
  • MDL Number:MFCD00010755
  • Synonyms:Di-tert-butylchlorosilane 99%;CHLORO-DI-TERT-BUTYLSILANE;DI-T-BUTYLCHLOROSILANE;DI-TERT-BUTYLCHLOROSILANE;Silane, chlorobis(1,1-dimethylethyl)-;DI-TERT-BUTYLCHLOROSILANE USP/EP/BP
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  • AHH
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 1G
  • 10G
  • 100g
  • 1KG
  • ManufacturerAHH
  • Product numberMT-08235
  • Product descriptionDi-tert-butylchlorosilane 99%
  • Packaging100g
  • Price$615
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0000356
  • Product descriptionDI-TERT-BUTYLCHLOROSILANE 95.00%
  • Packaging1G
  • Price$149.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0000356
  • Product descriptionDI-TERT-BUTYLCHLOROSILANE 95.00%
  • Packaging10G
  • Price$1281.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0000356
  • Product descriptionDI-TERT-BUTYLCHLOROSILANE 95.00%
  • Packaging1KG
  • Price$9975
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number296937
  • Product descriptionDi-tert-butylchlorosilane 97%
  • Packaging10g
  • Price$263
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-08235 Di-tert-butylchlorosilane 99% 100g $615 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000356 DI-TERT-BUTYLCHLOROSILANE 95.00% 1G $149.88 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000356 DI-TERT-BUTYLCHLOROSILANE 95.00% 10G $1281.88 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000356 DI-TERT-BUTYLCHLOROSILANE 95.00% 1KG $9975 2021-12-16 Buy
Sigma-Aldrich 296937 Di-tert-butylchlorosilane 97% 10g $263 2024-03-01 Buy

Properties

Boiling point :82-84 °C/45 mmHg (lit.)
Density :0.884 g/mL at 25 °C (lit.)
refractive index :n20/D 1.441(lit.)
Flash point :103 °F
form :Liquid
color :Clear colorless
Specific Gravity :0.884
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :2203045
Stability :Stable. Flammable. Incompatible with strong oxidizing agents.
CAS DataBase Reference :56310-18-0

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Considerable study of alkoxysilanes as intramolecular hydrogen transfer agents has been undertaken.The di-t-butyloxysilanes, prepared from di-tbutylchlorosilane and the requisite alcohol, are particularly effective and are generally stable to column chromatography.
Treatment of a γ-iodoallylic alcohol with NaH and t-Bu2SiHCl afforded the corresponding di-t-butyloxysilanes which were exposed to UV irradiation in the presence of 10% hexabutylditin in the so-called unimolecular chain transfer (UMCT) reaction of silicon hydrides to afford the reduced alkene (eq 1).reaction of silicon hydrides

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