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ChemicalBook >> CAS DataBase List >> Phenoxyacetyl chloride

Phenoxyacetyl chloride

Phenoxyacetyl chloride price.
  • $10 - $844.91
  • Product name: Phenoxyacetyl chloride
  • CAS: 701-99-5
  • MF: C8H7ClO2
  • MW: 170.59
  • EINECS:211-862-4
  • MDL Number:MFCD00000726
  • Synonyms:AKOS BBS-00003927;PHENOXYACETYL CHLORIDE;Acyl chloride kind;Acetylchloride,phenoxy-;LABOTEST-BB LT00643586;phenoxy-acetylchlorid ;Phenyloxyacetyl chloride;Phenoxyacetic acid chloride
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  • AHH
  • AK Scientific
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Frontier Specialty Chemicals
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
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  • ManufacturerAHH
  • Product numberMT-20925
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging1000g
  • Price$496
  • Updated2021-12-16
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  • ManufacturerAK Scientific
  • Product numberJ56760
  • Product descriptionPhenoxyacetyl chloride
  • Packaging4x25g
  • Price$150
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product numberA13761
  • Product descriptionPhenoxyacetyl chloride, 98%
  • Packaging50g
  • Price$54.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberA13761
  • Product descriptionPhenoxyacetyl chloride, 98%
  • Packaging250g
  • Price$179.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberA13761
  • Product descriptionPhenoxyacetyl chloride, 98%
  • Packaging1000g
  • Price$564
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0156783
  • Product descriptionPHENOXYACETYL CHLORIDE 95.00%
  • Packaging1G
  • Price$628.51
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0156783
  • Product descriptionPHENOXYACETYL CHLORIDE 95.00%
  • Packaging5G
  • Price$844.91
  • Updated2021-12-16
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  • ManufacturerFrontier Specialty Chemicals
  • Product numberJK263774
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging10g
  • Price$25
  • Updated2021-12-16
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  • ManufacturerFrontier Specialty Chemicals
  • Product numberJK263774
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging50g
  • Price$70
  • Updated2021-12-16
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  • ManufacturerFrontier Specialty Chemicals
  • Product numberJK263774
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging250g
  • Price$220
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number099217
  • Product description2-Phenoxyacetylchloride 98%
  • Packaging1g
  • Price$10
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number158623
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging10g
  • Price$30.84
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number158623
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging50g
  • Price$88.2
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number158623
  • Product descriptionPhenoxyacetyl chloride 98%
  • Packaging250g
  • Price$140
  • Updated2024-03-01
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  • ManufacturerTCI Chemical
  • Product numberP0113
  • Product descriptionPhenoxyacetyl Chloride >98.0%(GC)(T)
  • Packaging25g
  • Price$30
  • Updated2024-03-01
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  • ManufacturerTCI Chemical
  • Product numberP0113
  • Product descriptionPhenoxyacetyl Chloride >98.0%(GC)(T)
  • Packaging500g
  • Price$350
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-20925 Phenoxyacetyl chloride 98% 1000g $496 2021-12-16 Buy
AK Scientific J56760 Phenoxyacetyl chloride 4x25g $150 2021-12-16 Buy
Alfa Aesar A13761 Phenoxyacetyl chloride, 98% 50g $54.65 2024-03-01 Buy
Alfa Aesar A13761 Phenoxyacetyl chloride, 98% 250g $179.65 2024-03-01 Buy
Alfa Aesar A13761 Phenoxyacetyl chloride, 98% 1000g $564 2021-12-16 Buy
American Custom Chemicals Corporation CHM0156783 PHENOXYACETYL CHLORIDE 95.00% 1G $628.51 2021-12-16 Buy
American Custom Chemicals Corporation CHM0156783 PHENOXYACETYL CHLORIDE 95.00% 5G $844.91 2021-12-16 Buy
Frontier Specialty Chemicals JK263774 Phenoxyacetyl chloride 98% 10g $25 2021-12-16 Buy
Frontier Specialty Chemicals JK263774 Phenoxyacetyl chloride 98% 50g $70 2021-12-16 Buy
Frontier Specialty Chemicals JK263774 Phenoxyacetyl chloride 98% 250g $220 2021-12-16 Buy
Oakwood 099217 2-Phenoxyacetylchloride 98% 1g $10 2021-12-16 Buy
Sigma-Aldrich 158623 Phenoxyacetyl chloride 98% 10g $30.84 2024-03-01 Buy
Sigma-Aldrich 158623 Phenoxyacetyl chloride 98% 50g $88.2 2024-03-01 Buy
Sigma-Aldrich 158623 Phenoxyacetyl chloride 98% 250g $140 2024-03-01 Buy
TCI Chemical P0113 Phenoxyacetyl Chloride >98.0%(GC)(T) 25g $30 2024-03-01 Buy
TCI Chemical P0113 Phenoxyacetyl Chloride >98.0%(GC)(T) 500g $350 2024-03-01 Buy

Properties

Melting point :100-100.5 °C
Boiling point :225-226 °C (lit.)
Density :1.235 g/mL at 25 °C (lit.)
refractive index :n20/D 1.534(lit.)
Flash point :227 °F
storage temp. :Store at RT.
form :Liquid
color :Clear slightly yellow to brown
Water Solubility :Reacts with water.
Sensitive :Moisture Sensitive
BRN :607585
CAS DataBase Reference :701-99-5(CAS DataBase Reference)
NIST Chemistry Reference :Acetyl chloride, phenoxy-(701-99-5)
EPA Substance Registry System :Acetyl chloride, phenoxy- (701-99-5)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Acylation of D- and DL-WV with phenoxyacetyl chloride, followed by cleavage of the t-butyl ester,afforded the penultimate penicilloic acids. Phenoxyacetyl chloride was used in the synthesis of series of macrocyclic bis-β-lactams, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester, N-protected guanosine derivatives, useful in RNA synthesis, phenyloxyketene, for cycloaddition to imines leading to β-lactams. Treatment of iminophosphoranes with phenoxyacetyl chloride afforded respectively the trans- and cis-3-(acylamino)-p-lactams. By the oxidative addition of stannous fluoride to allyliodide, with 1, 2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallylester, which is in turn converted into 2-deoxy-D-ribose. The 4-disubstituted P-lactams (4a-c and 6a-b) were prepared through the reaction of N,N-diphenylhydrazones and N-methyl-N-phenylhydrazones of ketones with phenoxyacetyl chloride/Et3N in dichloromethane.

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