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(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol

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(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Basic information
Product Name:(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol
Synonyms:(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol;Sparsiflorine;4H-Dibenzo[de,g]quinoline-1,10-diol, 5,6,6a,7-tetrahydro-2-methoxy-, (6aS)-
CAS:2128-61-2
MF:C17H17NO3
MW:283.32
EINECS:
Product Categories:
Mol File:2128-61-2.mol
(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Structure
(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Chemical Properties
Melting point 230-232 °C (decomp)
Boiling point 528.0±50.0 °C(Predicted)
density 1.320±0.06 g/cm3(Predicted)
pka9?+-.0.20(Predicted)
Safety Information
MSDS Information
(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Usage And Synthesis
DescriptionThe leaves of Croton sparsijlorus Morung yield this noraporphine alkaloid which crystallizes as colourless, slender needles from EtOH. Two hydroxyl groups and an imino group are present and the base yields crystalline salts and derivatives, e.g. the hydrochloride, [α]30D + 43° (H20); methiodide, m.p. 218°C (dec.); the O,N-diacetyl derivative, m.p. 245°C and the triacetyl derivative, m.p. 196-7°C. The N-methyl compound gives a crystalline methiodide, m.p. 236-8°C (dec.). The structure has been established as 2-methoxy-l : 10-dihydroxynor aporphine.
ReferencesChatterjee et al., Tetrahedron Lett., 1539 (1965)
(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Preparation Products And Raw materials
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