17β,23β-Epoxyveratraman-3β,11β-diol

17β,23β-Epoxyveratraman-3β,11β-diol Basic information
Product Name:17β,23β-Epoxyveratraman-3β,11β-diol
Synonyms:17β,23β-Epoxyveratraman-3β,11β-diol;Veratrobasine;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridine]-3,11-diol, 1,2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11,11a,11b-octadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11R,11aS,11bR)-
CAS:20226-97-5
MF:C27H41NO3
MW:427.62
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Mol File:20226-97-5.mol
17β,23β-Epoxyveratraman-3β,11β-diol Structure
17β,23β-Epoxyveratraman-3β,11β-diol Chemical Properties
Melting point 285-8°C
Safety Information
MSDS Information
17β,23β-Epoxyveratraman-3β,11β-diol Usage And Synthesis
DescriptionA steroidal alkaloid of Veratrum album, the base crystallizes as colourless prisms. It has [α]20D - 126° (c 0.65, pyridine) and - 76.6° (c 0.58, EtOH). The sulphate yields colourless crystals from aqueous EtOH, m.p. 250-3°C (dec.); [α]20D° - 175° (c 0.22, 75% EtOH) and the acetyl derivative forms prisms from Me2CO with one mole of solvent. The structure has been confirmed by the total synthesis of the alkaloid.
ReferencesKutney et al., Intrasci. Chem. Rep., 4, 265 (1970)
17β,23β-Epoxyveratraman-3β,11β-diol Preparation Products And Raw materials
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