isocorybulbine

isocorybulbine Basic information
Product Name:isocorybulbine
Synonyms:isocorybulbine;[13S,13aβ,(+)]-5,8,13,13a-Tetrahydro-3,9,10-trimethoxy-13-methyl-6H-dibenzo[a,g]quinolizine-2-ol;6H-Dibenzo[a,g]quinolizin-2-ol, 5,8,13,13a-tetrahydro-3,9,10-trimethoxy-13-methyl-, (13S,13aR)-
CAS:22672-74-8
MF:C21H25NO4
MW:355.43
EINECS:
Product Categories:
Mol File:22672-74-8.mol
isocorybulbine Structure
isocorybulbine Chemical Properties
Melting point 179-180°; also given as 187-188°
alpha D15 +301° in chloroform
Boiling point 488.45°C (rough estimate)
density 1.0450
refractive index 1.5614 (estimate)
pka10.18±0.40(Predicted)
Safety Information
MSDS Information
isocorybulbine Usage And Synthesis
DescriptionThis alkaloid, isomeric with corybulbine (q.v.) is present in Corydalis tuberosa D.C. and may be purified from EtOH when it yields colourless, flat leaflets which are only slightly soluble in EtOH. The base is dextrorotatory with [α]29Dl>s + 301° (CHC13). It furnishes a crystalline methiodide, m.p. 218-221 0c.
ReferencesBruchhausen, Stippler., Chern. Abstr., 21, 1963 (1927) Spath, Holter., Ber., 59,2800 (1926)
isocorybulbine Preparation Products And Raw materials
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