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(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS

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(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Suppliers list
Company Name: Hangzhou MolCore BioPharmatech Co.,Ltd.
Tel: +86-057181025280; +8617767106207
Email: sales@molcore.com
Products Intro: Product Name:(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane
CAS:325168-89-6
Purity:NLT 98% Remarks:MC548669
Company Name: J & K SCIENTIFIC LTD.  
Tel: 010-82848833 400-666-7788
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Products Intro: Product Name:(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS
CAS:325168-89-6
Purity:min. 97% Package:100mg;500mg
Company Name: Alfa Aesar  
Tel: 400-6106006
Email: saleschina@alfa-asia.com
Products Intro: Product Name:(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane, CTH-(R)-3,5-xylyl-PHANEPHOS
CAS:325168-89-6
Package:0.1g Remarks:044615
Company Name: Energy Chemical  
Tel: 021-021-58432009 400-005-6266
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Products Intro: Product Name:(R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane
CAS:325168-89-6
Purity:97% Package:100MG,500MG
Company Name: Daicel Chiral Technologies (China)CO.,LTD  
Tel: 021-50460086-9 15921403865
Email: han_yajun@dctc.daicel.com
Products Intro: Product Name:(R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane
CAS:325168-89-6
Purity:95%/98% Package:100MG;100G; 1KG Remarks:201326
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Basic information
Reaction
Product Name:(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS
Synonyms:(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS;(R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene;(R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene;(R)-Xylyl-PHANEPhos;(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS;(R)-XylPhanePHOS;(R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane;Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer
CAS:325168-89-6
MF:C48H50P2
MW:688.86
EINECS:
Product Categories:PHANEPhos Series;Chiral Phosphine;organophosphine ligand
Mol File:325168-89-6.mol
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Structure
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Chemical Properties
Melting point 234-238 °C
Boiling point 785.2±60.0 °C(Predicted)
form Powder
color white
optical activity[α]22/D -61.0, c = 0.1 in ethanol
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26
WGK Germany 3
MSDS Information
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Usage And Synthesis
Reaction
  1. Chiral ligand employed in the enantioselective hydrogenation of various ketones.
  2. Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
  3. Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
  4. Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
Reactions of 325168-89-6
UsesEfficient ligand for asymmetric hydrogenation of dehydroamino acids, methyl esters and ketones.
(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Preparation Products And Raw materials
Tag:(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS(325168-89-6) Related Product Information
[2.2]Paracyclophane