Log in | Join Free | china | japan | germany

(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol

Request For Quotation
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Suppliers list
Company Name: Shaanxi Didu New Materials Co. Ltd
Tel: +86-89586680 +86-13289823923
Email: 1026@dideu.com
Products Intro: Product Name:Retamine;2122-29-4
CAS:2122-29-4
Purity:0.99 Package:25KG,200L
Company Name: TargetMol Chemicals Inc.
Tel: +1-781-999-5354
Email: support@targetmol.com
Products Intro: Product Name:Retamine
CAS:2122-29-4
Package:100 mg；500 mg Remarks:REAGENT;FOR LABORATORY USE ONLY
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Basic information
Product Name:(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol
Synonyms:(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol;(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1β-ol;Retamine;7,14-Methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol, dodecahydro-, (1S,7R,7aS,14R,14aS)-
CAS:2122-29-4
MF:C15H26N2O
MW:250.38
EINECS:
Product Categories:
Mol File:2122-29-4.mol
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Structure
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Chemical Properties
Melting point 165-166°
alpha D20 +46.2° (c = 1.017 in abs ethanol)
Safety Information
MSDS Information
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Usage And Synthesis
DescriptionThis sparteine alkaloid was first isolated by Battandier and Malosse from Retama sphaerocarpa Boiss. and found to give colour reactions suggesting a relationship with sparteine. It has [α]20D + 46.2° (c 1.017, EtOH) and yields crystalline salts and derivatives including the hydrochloride, m.p. 272-3°C; picrate, m.p. 165- 6°C; phenylurethane, m.p. 190-1 °c and the acetyl derivative as hygroscopic crystals, m.p. about 60°C. The earlier structure as 8-hydroxysparteine has been shown to be wrong, the correct structure, established by synthesis, being 12-{3- hydroxysparteine.
ReferencesBattandier, Malosse., Compt. rend., 125, 360,450 (1897)
Ribas, Sanchez, Primo., Anales, [is. y. quim., 42, 516 (1946)
Ribas, Fraga., Anales. Real. Soc. Espan [is. y. QUim., 45B, 1426 (1949)
Ribas, Fraga., ibid, 46B, 665 (1950)
Fragaetal., Tetrahedron, 11,78 (1960)
Revised structure:
Bohlmann et al., Chem. Ber., 98, 653, 659 (1965)
Ribas, Castedo, Garcfa., Tetrahedron Lett., 3181 (1965)
Shin, Fonzes, Marion., Can. 1. Chem., 43,2012 (1965)
(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol Preparation Products And Raw materials
Tag:(1S,7aβ,14aα)-Dodecahydro-7β,14β-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-1-ol(2122-29-4) Related Product Information