Thiophosgene

Price	$1	$2
Package	1KG	1KG

Product Details

Product Name: Thiophosgene	CAS No.: 463-71-8
Min. Order: 1KG	Purity: 98%
Supply Ability: 200kg	Release date: 2019/09/02
Product No:: Cindy 37

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Product Name:

Thiophosgene

Synonyms:

thio-carbonicdichlorid;thiocarbonicdichloride;Thiocarbonyl dichloride;thio-carbonylchlorid;thiocarbonyldichloride;Thiofosgen;Carbon chlorosulfide;carbonchlorosulfide

CAS:

463-71-8

MF:

CCl2S

MW:

114.98

EINECS:

207-341-6

Product Categories:

TCI-;-;Organics

Mol File:

463-71-8.mol

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Thiophosgene Chemical Properties

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Boiling point

73 °C

density

1.508

vapor density

4 (vs air)

refractive index

n20/D 1.548(lit.)

Fp

62 °C

storage temp.

2-8°C

form

Solid

color

White to yellow

Water Solubility

slow decomposition in cold, fast in hot water

BRN

1633495

Stability:

Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.

CAS DataBase Reference

463-71-8(CAS DataBase Reference)

NIST Chemistry Reference

Carbonothioic dichloride(463-71-8)

EPA Substance Registry System

Carbonothioic dichloride(463-71-8)

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Safety Information

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Hazard Codes

T

Risk Statements

22-23-36/37/38

Safety Statements

7-9-36/37-45-7/9

RIDADR

UN 2474 6.1/PG 2

WGK Germany

1

RTECS

XN2450000

F

19-21

HazardClass

6.1(a)

PackingGroup

II

HS Code

28530090

Hazardous Substances Data

463-71-8(Hazardous Substances Data)

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MSDS Information

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Provider Language

Thiophosgene

English

ACROS

English

SigmaAldrich

English

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Thiophosgene Usage And Synthesis

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Chemical Properties

Reddish liquid. Decomposes in water and alcohol; soluble in ether.

Chemical Properties

A clear dark red to reddish-yellow liquid. Sharp, choking odor.

Uses

Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

General Description

A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.

Air & Water Reactions

Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.

Reactivity Profile

Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.

Potential Exposure

Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.

Shipping

UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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Thiophosgene Preparation Products And Raw materials

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Raw materials

Potassium iodide-->Sulfur dioxide-->1,1,2,2-Tetrachloroethane-->Perchloromethylmercaptan

Preparation Products

Fluorescein isothiocyanate isomer I-->5-ISOTHIOCYANATO-1,3-DIMETHYL-1H-PYRAZOLE-->2-(1,3-DIMETHYL-1H-PYRAZOL-5-YL)ETHENETHIONE-->3-ISOTHIOCYANATO-1,5-DIMETHYL-1H-PYRAZOLE-->2-ISOTHIOCYANATO-4,6-DIMETHOXYPYRIMIDINE-->5-BROMO-6-ISOTHIOCYANATE QUINOXALINE-->3,4-METHYLENEDIOXYPHENYL ISOTHIOCYANATE-->Amoscanate-->4-(1H-PYRAZOL-1-YL)PHENYL ISOTHIOCYANATE-->4-phenoxy-2，6-diisopropyl phenyl isothiocyanate-->1,4-PHENYLENE DIISOTHIOCYANATE-->DI-2-PYRIDYL THIONOCARBONATE-->4-CARBOXYPHENYL ISOTHIOCYANATE-->3-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE-->2-ETHOXYPHENYL ISOTHIOCYANATE-->2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL ISOTHIOCYANATE-->3,5-DIMETHYLPHENYL ISOTHIOCYANATE-->2-CHLORO-4-METHYLPHENYL ISOTHIOCYANATE-->4-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE-->3,5-DIMETHOXYPHENYL ISOTHIOCYANATE

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates： Pharmaceutical intermediates; OLED intermediates;

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Product Details

Company Profile Introduction

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