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Barium hydroxide octahydrate(12230-71-6)

Barium hydroxide octahydrate(12230-71-6)
Product IdentificationBack to Contents
【Product Name】

Barium hydroxide octahydrate
【Synonyms】

Barium dihydroxide octahydrate
【CAS】

12230-71-6
【Formula】

BaH18O10
【Molecular Weight】

315.45999999999998
【EINECS】

241-234-5
【RTECS】

CQ9200000
【Merck】

13,980
【Beilstein/Gmelin】

22362 (G)
【EC Class】

harmful, corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

Transparent, odorless solid.
【Solubility in water】

56 g/L
【Melting Point】

78
【Density】

2.18 g/cm3 (20 C)
【Usage】

Titration of weak acids, particularly organic acids. Used in organic synthesis as a strong base.
【Vapor Density】

10.9
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Corrosives area.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Inhalation】

May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns. Contact produces irritation, tearing, and burning pain.
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause respiratory failure. May cause kidney failure. May cause convulsions, increased blood pressure, muscle spasms, and possible paralysis.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 20/22 34
【EC Safety Phrase】

S 26 28 36/37/39 45
【UN (DOT)】

3262
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
【Exposure limit(s)】

OSHA TWA: 0.5 mg/m3 as Ba.
【Poison Class】

2 (Very strong toxins)
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, barium oxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3262
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2816 40 00
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