ChemicalBook >>2-Nitrotoluene>>alpha-Methylnitrobenzene(88-72-2)

alpha-Methylnitrobenzene(88-72-2)

alpha-Methylnitrobenzene(88-72-2)
Product IdentificationBack to Contents
【Product Name】

alpha-Methylnitrobenzene
【Synonyms】

1-Methyl-2-nitrobenzene
2-Methylnitrobenzene
2-Nitrotoluene
Methylnitrobenzene
【CAS】

88-72-2
【Formula】

C7H7NO2
【Molecular Weight】

137.13999999999999
【EINECS】

201-853-3
【RTECS】

XT3150000
【RTECS Class】

Tumorigen; Mutagen; Reproductive Effector
【Merck】

12,6748
【Beilstein/Gmelin】

1907580
【Beilstein Reference】

4-05-00-00845
【EC Index Number】

609-006-00-3
【EC Class】

Toxic; Danger of cumulative effects; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Yellow liquid with an almond-like odor.
【Solubility in water】

0.7 g/L
【Melting Point】

-4 - -3
【Boiling Point】

221.7
【Vapor Pressure】

0.29 (25 C)
【Density】

1.163 g/cm3 (20 C)
【Partition Coefficient】

2.3
【Heat Of Vaporization】

59.1 kJ/mol
【Heat Of Combustion】

-3597 kJ/mol
【Usage】

For production of toluidine, tolidine, fuchsine, and various synthetic dyes.
【Vapor Density】

4.72
【Saturation Concentration】

0.01% (20 C)
【Odor threshold】

0.05 mg/L
【Refractive Index】

1.5450 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale.
Hazards IdentificationBack to Contents
【Inhalation】

May be fatal if inhaled. Causes respiratory tract irritation. Aspiration may cause respiratory swelling and pneumonitis.
【Skin】

Causes mild skin irritation.
【Eyes】

Causes mild eye irritation.
【Ingestion】

Aspiration hazard. May be harmful if swallowed. Causes digestive tract irritation.
【Hazards】

Containers may explode when heated.
【EC Risk Phrase】

R 23/24/25 33 51/53
【EC Safety Phrase】

S 28 37 45 61
【UN (DOT)】

1664
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%.
【Exposure limit(s)】

TLV (as TWA): 2 ppm; 11 mg/m3 (skin) (ACGIH 1991-1992). OSHA PEL: TWA 5 ppm (30 mg/m3) skin NIOSH REL: TWA 2 ppm (11 mg/m3) skin NIOSH IDLH: 200 ppm
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

106
【Autoignition】

420
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam.
【Upper exp. limit】

8.8
【Lower exp. limit】

1.47
【Fire Potential】

Moderately flammable. Combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

9
【Incompatibilities】

Oxidizing agents
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】

Toxic fumes may be generated.
Transport InformationBack to Contents
【UN Number】

1664
【Hazard Class】

6.1
【Packing Group】

II
【HS Code】

2904 20 00
Company Name: Shandong Xinxian Yingtai Chemical Co., Ltd
Tel: 0635-7888358 15550585968
Fax:
WebSite: yingtai.cnadc.com.cn/
Company Name: Yangzhou juhechang Technology Co., Ltd
Tel: 0514-0514-83662002 13073488988
Fax: 0514-83662002
WebSite: www.yzjhc.net/
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel: 021-61259108 18621169109
Fax: 86-21-61259102
WebSite: www.meryer.com/cn/index/
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.
Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
WebSite: https://www.chemicalbook.com/ShowSupplierProductsList13285/0.htm
Company Name: Alfa Aesar
Tel: 400-6106006
Fax: 021-67582001/03/05
WebSite: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.
Tel: 021-67121386
Fax: 021-67121385
WebSite: https://www.tcichemicals.com/CN/zh/
Company Name: Energy Chemical
Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
WebSite: http://www.energy-chemical.com
Company Name: Beijing Ouhe Technology Co., Ltd
Tel: 010-82967028 13552068683
Fax: +86-10-82967029
WebSite: http://www.ouhechem.com/