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Allylpalladium chloride dimer(12012-95-2)

Allylpalladium chloride dimer(12012-95-2)
Product IdentificationBack to Contents
【Product Name】

Allylpalladium chloride dimer
【Synonyms】

Bis(allyl)dichlorodipalladium
Bis(allylchloropalladium)
Diallyldichlorodipalladium
Palladium, di-m-chlorobis(h3-2-propenyl)di-
【CAS】

12012-95-2
【Formula】

C6H10Cl2Pd2
【Molecular Weight】

365.85
【EINECS】

234-579-8
【RTECS】

RT3510000
【RTECS Class】

Organometallic; Primary Irritant
【Beilstein/Gmelin】

4124623
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Yellow crystalline powder.
【Solubility in water】

Insoluble
【Melting Point】

160
【Usage】

Catalyst used in organic synthesis.
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Use with adequate ventilation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Use only in a chemical fume hood. Keep from contact with moist air and steam. Do not breathe dust.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can produce delayed pulmonary edema.
【Skin】

Causes severe skin irritation.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【EC Risk Phrase】

R 36/37/38
【EC Safety Phrase】

S 26 36
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Disposal Code】

27
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions. May decompose on exposure to moist air or water.
【Incompatibilities】

Strong oxidizing agents, moisture, air.
【Decomposition】

Hydrogen chloride, carbon monoxide, carbon dioxide, chloride fumes.
Transport InformationBack to Contents
【UN Number】

1759
【HS Code】

2843 90 90
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