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Potassium hexacyanocobaltate(III)(13963-58-1)

Potassium hexacyanocobaltate(III)(13963-58-1)
Product IdentificationBack to Contents
【Product Name】

Potassium hexacyanocobaltate(III)
【Synonyms】

Potassium cobalticyanide
【CAS】

13963-58-1
【Formula】

C6CoK3N6
【Molecular Weight】

332.33
【EINECS】

237-742-1
【RTECS】

GF9470000
【RTECS Class】

Other
【Merck】

12,7801
【Beilstein/Gmelin】

21682 (G)
Physical and Chemical PropertiesBack to Contents
【Appearance】

Moist, light-yellow crystals crystals.
【Density】

1.87 g/cm3
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light.
【Handling】

Wash thoroughly after handling. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light. Use only in a chemical fume hood. Wash clothing before reuse.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Harmful if inhaled.
【Skin】

May cause skin irritation. Harmful if absorbed through the skin.
【Eyes】

May cause eye irritation.
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract.
【Hazards】

Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Contact with metals may evolve flammable hydrogen gas.
【UN (DOT)】

1588
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Experimental carcinogen.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water. Stop leak only if you can do so without risk.
Stability and ReactivityBack to Contents
【Stability】

Contact with acid liberates gas. Sensitive to Light.
【Incompatibilities】

Strong oxidizing agents, strong acids.
【Decomposition】

Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】

Fire will produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1588
【Hazard Class】

6.1
【Packing Group】

I; II; III
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