ChemicalBook >>trans-1,4-Dichloro-2-butene>>(E)-1,4-Dichloro-2-butene(110-57-6)

(E)-1,4-Dichloro-2-butene(110-57-6)

(E)-1,4-Dichloro-2-butene(110-57-6)
Product IdentificationBack to Contents
【Product Name】

(E)-1,4-Dichloro-2-butene
【Synonyms】

1,4-Dichloro-trans-2-butene
2-Butene, 1,4-dichloro-, (2E)-
trans-1,4-Dichlorobuten-2-ene
【CAS】

110-57-6
【Formula】

C4H6Cl2
【Molecular Weight】

125
【EINECS】

203-779-7
【RTECS】

EM4903000
【RTECS Class】

Tumorigen
【Beilstein/Gmelin】

1719693
【Beilstein Reference】

4-01-00-00787
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid with a distinct odor.
【Solubility in water】

Slightly soluble
【Melting Point】

1
【Boiling Point】

156
【Vapor Pressure】

3.9 (25 C)
【Density】

1.1873 g/cm3 (20 C)
【Heat Of Vaporization】

37.6 kJ/mol
【Heat Of Combustion】

-5063 kJ/mol
【Usage】

Chemical intermediate for hexamethylenediamine & chloroprene.
【Refractive Index】

1.4870 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Keep under an argon blanket. Refrigerator (approx 4 C).
【Handling】

Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

May be fatal if inhaled. Causes chemical burns to the respiratory tract. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth.
【Skin】

Causes skin burns. Toxic in contact with skin.
【Eyes】

Causes eye burns. Lachrymator.
【Ingestion】

Poison by ingestion. Causes gastrointestinal tract burns.
【Hazards】

The material will burn, though it may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, it emits toxic fumes of chlorine-containing compounds.
【UN (DOT)】

2927
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause cancer in humans.
Fire Fighting MeasuresBack to Contents
【Flash Point】

54
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Upper exp. limit】

4
【Lower exp. limit】

1.5
【Fire Potential】

Flammable dichlorobutene
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Stability and ReactivityBack to Contents
【Stability】

Reacts slowly with water to form hydrochloric acid.
【Incompatibilities】

Strong oxidizing agents, strong bases.
【Decomposition】

Hydrogen chloride, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2927
【Hazard Class】

6.1
【Packing Group】

I; II
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