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ChemicalBook CAS DataBase List (3-Bromo-2-nitrophenyl)methanol

(3-Bromo-2-nitrophenyl)methanol synthesis

6synthesis methods
585-76-2 Synthesis
3-Bromobenzoic acid

585-76-2
337 suppliers
$6.00/5g

(5-bromo-2-nitrophenyl)methanol

1241894-37-0
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(3-Bromo-2-nitrophenyl)methanol

1261475-45-9
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Yield:1241894-37-0 610 mg

Reaction Conditions:

Stage #1: m-bromobenzoic acidwith sulfuric acid;nitric acid at 0;
Stage #2: with borane-THF in tetrahydrofuran at 20;Inert atmosphere;
Stage #3: with methanol in tetrahydrofuran;

References:

Jacquart, Aurelie;Tauc, Patrick;Pansu, Robert B.;Ishow, Elena [Chemical Communications,2010,vol. 46,# 24,p. 4360 - 4362] Location in patent:supporting information; experimental part