ChemicalBook CAS DataBase List 5-Methyl-2-hexanone

5-Methyl-2-hexanone synthesis

10synthesis methods

Product Name:5-Methyl-2-hexanone
CAS Number:110-12-3
Molecular formula:C7H14O
Molecular Weight:114.19

5-Methyl-2-hexanone is produced by condensation of acetone with isobutyraldehyde. This reaction may be carried out in one or two steps, in the liquid or in the gas phase.

5166-53-0
66 suppliers
$79.00/25mL

110-12-3
186 suppliers
$10.00/5mL

Yield:110-12-3 88 %Chromat.

Reaction Conditions:

with methanol;C₂₅H₂₉ClNO₂Rh;potassium carbonate at 90; for 1 h;chemoselective reaction;

Steps:

2.2. Transfer hydrogenation of unsaturated ketones in methanol
A Radley tube was charged with an unsaturated ketone (0.3mmol), catalyst (0.003 mmol) and K2CO3 (0.25 eq), to which was introduced MeOH (1.5 mL). The reaction mixture was heated to reflux at 90 °C for 1 h. The resulting mixture was then cooled to room temperature, followed by solvent evaporation under vacuum. The product was purified by flash column chromatography (hexane/ethyl acetate, 4:1).

References:

Aboo, Ahmed H.;Begum, Robina;Zhao, Liangliang;Farooqi, Zahoor H.;Xiao, Jianliang [Cuihua Xuebao/Chinese Journal of Catalysis,2019,vol. 40,# 11,p. 1795 - 1799]

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3524-73-0
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$45.00/50mg

110-12-3
186 suppliers
$10.00/5mL

References

624-44-2
33 suppliers
$102.00/25mL

110-12-3
186 suppliers
$10.00/5mL

References

627-59-8
92 suppliers
$20.00/1g

110-12-3
186 suppliers
$10.00/5mL

References

Silane, trimethyl[(4-methyl-1-methylenepentyl)oxy]-

73503-97-6
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110-12-3
186 suppliers
$10.00/5mL

References

5-Methyl-2-hexanone Related Search:

Clomazone 4-Methyl-2-pentanone 2-Hexanone 2,2'-Azobis(2,4-dimethyl)valeronitrile 4-Heptanone Isophorone diisocyanate PALATINOSE Methyl acetate Methyl salicylate Cyclohexanone