ChemicalBook CAS DataBase List ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE

ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE synthesis

8synthesis methods

Product Name:ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE
CAS Number:19247-87-1
Molecular formula:C14H12O4
Molecular Weight:244.24

2689-65-8
142 suppliers
$24.73/1gm:

51934-41-9 Synthesis

51934-41-9
287 suppliers
$6.00/5g

19247-87-1
60 suppliers
$60.00/100mg

Yield: 78%

Reaction Conditions:

Stage #1:5-iodofuran-2-carbaldehyde with indium;octadecane;lithium chloride in tetrahydrofuran at 30; for 0.333333 h;
Stage #2:4-iodobenzoic acid ethyl ester with (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran;1-methyl-pyrrolidin-2-one at 25; for 1.5 h;Inert atmosphere;

References:

Chen, Yi-Hung;Knochel, Paul [Angewandte Chemie - International Edition,2008,vol. 47,# 40,p. 7648 - 7651] Location in patent:supporting information; experimental part

27329-70-0 Synthesis