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ChemicalBook CAS DataBase List TITANIUM MONOXIDE

TITANIUM MONOXIDE synthesis

2synthesis methods
Titanium monoxide or hongquiite (TiO) may be prepared by direct reduction by mixing stoichiometric amounts of titanium metal and titanium dioxide into a molybdenum crucible at 1600°C or reduction of the titanium dioxide with hydrogen under pressure at 130 atm and 2000°C.
Ti (s) + TiO2(s) —> 2 TiO(s) (1600°C)
-

Yield:-

Reaction Conditions:

with carbon monoxide;ozone in gas;byproducts: O2; titanium atoms vaporized from a filament of Ti deposited on a molybdenum base (heating to 1350-2400 K, vapor pressure: 1E-2 to 1E-1 Torr), entrained in CO (ca. 2.5 Torr), oxidized with O3, Ti(CO)x as intermediate, TiO formed in excited states; luminescence spectroscopy;

References:

McQuaid, M. J.;Morris, K.;Gole, J. L. [Journal of the American Chemical Society,1988,vol. 110,# 16,p. 5280 - 5285]

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