ChemicalBook--->CAS DataBase List--->100163-29-9

100163-29-9

100163-29-9 Structure

100163-29-9 Structure
IdentificationBack Directory
[Name]

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
[CAS]

100163-29-9
[Synonyms]

RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM
(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
Rac-Ethylenebis(4,5,7-tetrahydro-1-indenyl)zirconium(Ⅳ)Dichloride
RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV)
RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE
DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
DICHLORO-(R,R)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium
[Molecular Formula]

C20H24Cl2Zr 10*
[MDL Number]

MFCD00672123
[MOL File]

100163-29-9.mol
[Molecular Weight]

426.53
Chemical PropertiesBack Directory
[Melting point ]

267-271 °C(lit.)
[form ]

Powder
[color ]

white to pale yellow
[Sensitive ]

moisture sensitive
Questions And AnswerBack Directory
[Stability]

Stable under normal temperature and pressure, avoid contact with water and oxidants.
[Storage]

sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39-45-36
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
Hazard InformationBack Directory
[Chemical Properties]

White to pale yellow powder,it can carry out catalytic reaction.
[Uses]

Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines
[Uses]

Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.
[reaction suitability]

core: zirconium
reagent type: catalyst
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